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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Lithium formate with Sodium formate
Components:
(1) Lithium formate; LiCHO2; [556-63-8]
NIST Chemistry WebBook
for detail
(2) Sodium formate; NaCHO2; [141-53-7]
NIST Chemistry WebBook
for detail
Original Measurements:
Tsindrik, N.M., Zh. Obshch. Khim. 28, 830-4 (1958).
Variables:
Prepared By:
P. Baldini
Experimental Remarks:
Note 1:
There is a minimum at 170 ºC and 100x
2
= 50.
Note 2:
The system was investigated at 0≤ 100x
1
≤ 80.
Experimental Data:
(Notes on the Nomenclature)
(Please see footnotes following the table(s).)
t/°C
T/K
10
0
* Mole Fraction
1
258
531
0
250
523
5
242
515
10
232
505
15
224
497
20
214
487
25
204
477
30
194
467
35
182
455
40
176
449
45
170
443
50
175
448
55
184
457
60
196
469
65
208
481
70
220
493
75
232
505
80
Notes:
a
These values were calculated by the compiler.
Method/Apparatus/Procedure:
A visual polythermal method was used. The temperatures were measured with a Nichrome-Constantan thermouple.
Source and Purity of Materials:
Analytical grade materials were recrystallized twice. The extrapolated fusion temperature of the lithium formate was 273 °C.
Estimated Errors:
Solubility: No information is given.
Temperature: The compiler estimates the accuracy of the temperature measurement to be probably ± 0.2 K.
References:
1
E.I. Pochtakova, Zh. Neorg. Khim.
25
, 1147 (1980)(*); Russ. J. Inorg. Chem.
25
, 637 (1980).