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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1-Nitropropane with Uranium bis (nitrato-O) dioxohexahydrate
Components:
(1) 1-Nitropropane; C3H7NO2; [108-03-2]
NIST Chemistry WebBook
for detail
(2) Uranium bis (nitrato-O) dioxohexa-hydrate; UO2(NO3)2 ×6H2O; [13520-83-7]
NIST Chemistry WebBook
for detail
Original Measurements:
Warner, R.K., Austral. J. Appl. Sci. 4, 581-9 (1953).
Variables:
Temperature = 293 K
Prepared By:
V. P. Sazonov
Experimental Remarks:
The solubility of uranyl nitrate (2) in 1-nitropropane (1) at 20 °C (293 K, compiler) was reported to be 100 w
2
= 1.1. The corresponding mole fraction, x
2
, calculated by the compiler, is 0.003.
Experimental Data:
(Notes on the Nomenclature)
Method/Apparatus/Procedure:
The analytical method was used. A sample of (2) was placed with the appropriate amount of pure (1) in a small flask. The contents of the flask were warmed to 30 to 50°C, agitated with excess crystals of (2) for 15 min, and then placed in a constant temperature bath at 20°C with intermittent shaking for 6 to 8 h. Crystallization from the supersaturated solution occurred, and when equilibrium was reached the solution was quickly decanted, filtered to remove fine crystals, and placed in a stoppered flask at 20°C for analysis.
Source and Purity of Materials:
(1) Synthesized by standard method; thoroughly dried and fractionally distilled.
(2) Source not specified; A. R. grade; not purified.
Estimated Errors:
Solubility: ±0.2 g/100 g solution.
Temperature: ±0.05 K.