IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitroethane with 1-Decanol
Components:
   (1) 1-Decanol; C10H22O; [112-30-1]  NIST Chemistry WebBook for detail
   (2) Nitroethane; C2H5NO2; [79-24-3]  NIST Chemistry WebBook for detail
Original Measurements:
   Francis, A.W., J. Phys. Chem. 60, 20-7 (1956).

 Variables:
   Temperature = 273 K to 292 K

 Prepared By:
   V. P. Sazonov and N. I. Lisov

 Experimental Data:   (Notes on the Nomenclature)
  
Mutual solubility of nitroethane (1) and 1-decanol (2)
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
0.0273.2--alcohol-rich phase
6.0279.219.00.331alcohol-rich phase
10.0283.221.00.359alcohol-rich phase
18.4291.653.0 0.704 alcohol-rich phase
Mutual solubility of nitroethane (1) and 1-decanol (2)
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
0.0273.290.00.950nitroethane-rich phase
6.0279.284.00.917nitroethane-rich phase
10.0283.280.00.894nitroethane-rich phase
18.4291.653.00.704 (UCST)nitroethane-rich phase
 Method/Apparatus/Procedure:
   The observations were made after vigorously shaking on glass stoppered graduated tubes of about 15 mL capacity immersed in water baths in large Dewar flasks. The water was agitated with a rapid stream of air bubbles. The temperature was adjusted by adding small amounts of cooler or warmer water occasionally as required.

 Source and Purity of Materials:
   (1) Eastman Kodak Co.; distilled with 30 cm column with reflux; b. p. = 114-115 °C; n(20°C,D) = 1.3920, p(20°C) = 1046.9 g·L-1.
   (2) Source not specified; purified by crystallization; m. p. = 6.8 °C; n(20 °C,D) = 1.4372, p(20°C) = 831.8 g·L-1.

 Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.