IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Nitroethane with Tetradecanoic acid

Components:
   (1) Nitroethane; C2H5NO2; [79-24-3]  NIST Chemistry WebBook for detail
   (2) Tetradecanoic acid; C14H28O2; [544-63-8]  NIST Chemistry WebBook for detail

Original Measurements:
   Hoerr, C.W.; Ralston, A.W., J. Org. Chem. 9, 329-37 (1944).

Variables:
   Temperature = 273 K to 323 K

Prepared By:
   N. I. Lisov and V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
  
Solubility of tetradecanoic acid (2) in nitroethane (1)
t/°CT/K102 * Mass Fraction w2 (compiler)g2/g1Mole Fraction x2 (compiler)
0.0273.2 0.3 0.3 x 1020.001
10.0283.2 0.5 0.5 x 1020.002
20.0293.2 1.2 1.2 x 1020.003
30.0303.2 3.2 3.3 x 1020.011
40.0313.2 9.7 10.7 x 1020.034
50.0323.292.21180 x 1020.795
Method/Apparatus/Procedure:
   The synthetic method, as described in Hoerr et al.,1 was used. No details were reported.

Source and Purity of Materials:
   (1) Source not specified; purity not specified; dried and twice distilled.
   (2) Source not specified; purified according to Pool and Ralston2 f. p. = 54.15 °C.

Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.

References:
   1 C. W. Hoerr, E. F. Binkerd, W. O. Pool, and A. W. Ralston, J. Org. Chem. 9, 68 (1944).
   2 W. O. Pool and A. W. Ralston, Ind. Eng. Chem. 34, 1104 (1942).