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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Nitroethane with 1-Tetradecanol
Components:
(1) 1-Tetradecanol; C14H30O; [112-72-1]
NIST Chemistry WebBook
for detail
(2) Nitroethane; C2H5NO2; [79-24-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Hoerr, C.W.; Harwood, H.J.; Ralston, A.W., J. Org. Chem. 9, 267-80 (1944).
Variables:
Temperature = 283 K to 309 K
Prepared By:
N. I. Lisov, V. P. Sazonov and N. V. Sazonov
Experimental Remarks:
The solubilities of nitroethane (1) and 1-tetradecanol (2) in mass percent including the region of immiscible solution over the temperature range were presented in graphical form and in a table.
Monotectic equilibrium occurs at 295.4 K.
Experimental Data:
(Notes on the Nomenclature)
Mutual solubility of nitroethane (1) and 1-tetradecanol (2)
t/°C
T/K
10
2
* Mass Fraction w
1
g
2
/g
1
Mole Fraction x
1
(compiler)
Comment(s)
10.0
283.2
-
0.1 x 10
2
-
alcohol-rich phase
19.2*
292.4
-
- x 10
0
-
alcohol-rich phase
20.0
293.2
-
1.9 x 10
2
-
alcohol-rich phase
26.1*
299.3
-
- x 10
0
-
alcohol-rich phase
29.0*
302.2
-
- x 10
0
-
alcohol-rich phase
30.0
303.2
-
14.5 x 10
2
-
alcohol-rich phase
31.6*
304.8
-
- x 10
0
-
alcohol-rich phase
32.6*
305.8
20.3 a
- x 10
0
0.421
alcohol-rich phase
32.7*
305.9
-
- x 10
0
-
alcohol-rich phase
33.3*
306.5
30.7 b
- x 10
0
0.558
alcohol-rich phase
33.7*
307.0
-
- x 10
0
-
alcohol-rich phase
33.7*
307.0
12.3 a
- x 10
0
0.286
alcohol-rich phase
34.6*
307.8
41.6 b
- x 10
0
0.670
alcohol-rich phase
34.9*
308.1
-
- x 10
0
-
alcohol-rich phase
35.7*
308.9
5.2 a
- x 10
0
0.135
alcohol-rich phase
Mutual solubility of nitroethane (1) and 1-tetradecanol (2)
t/°C
T/K
10
2
* Mass Fraction w
1
g
2
/g
1
Mole Fraction x
1
(compiler)
Comment(s)
10.0
283.2
99.9 a
0.1 x 10
2
0.9996
nitroethane-rich phase
19.2*
292.4
98.3 a
- x 10
0
0.994
nitroethane-rich phase
20.0
293.2
98.1 a
1.9 x 10
2
0.993
nitroethane-rich phase
26.1*
299.3
94.2 a
- x 10
0
0.979
nitroethane-rich phase
29.0*
302.2
89.0 a
- x 10
0
0.958
nitroethane-rich phase
30.0
303.2
87.3 a
14.5 x 10
2
0.951
nitroethane-rich phase
31.6*
304.8
80.4 a
- x 10
0
0.921
nitroethane-rich phase
32.6*
305.8
-
- x 10
0
-
nitroethane-rich phase
32.7*
305.9
71.6 b
- x 10
0
0.878
nitroethane-rich phase
33.3*
306.5
-
- x 10
0
-
nitroethane-rich phase
33.7*
307.0
67.2 b
- x 10
0
0.854
nitroethane-rich phase
33.7*
307.0
-
- x 10
0
-
nitroethane-rich phase
34.6*
307.8
-
- x 10
0
-
nitroethane-rich phase
34.9*
308.1
54.8 b
- x 10
0
0.776
nitroethane-rich phase
35.7*
308.9
-
- x 10
0
-
nitroethane-rich phase
Notes:
*
The compilers extracted these data from the published graphs.
a
Solid-liquid equilibrium
b
Liquid-liquid equilibrium.
Method/Apparatus/Procedure:
The solubility measurements were made with the equipment and in the manner described in Hoerr et al.
1
and Ralston et al.
2
Source and Purity of Materials:
(1) Source not specified; purity not specified.
(2) Prepared by catalytic hydrogenation of methyl myristate; purified by vacuum distillation; f. p. = 38.26 °C.
Estimated Errors:
Solubility: Not specified.
Temperature: Not specified.
References:
1
C. W. Hoerr, E. F. Binkerd, W. O. Pool, and A. W. Ralston, J. Org. Chem. 9, 68 (1944).
2
A. W. Ralston, C. W. Hoerr, W. O. Pool, and H. J. Harwood, J. Org. Chem. 9, 102 (1944).