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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Nitroethane with N-Phenyldecanamide
Components:
(1) Nitroethane; C2H5NO2; [79-24-3]
NIST Chemistry WebBook
for detail
(2) N-Phenyldecanamide; C16H25NO; [15473-32-2]
NIST Chemistry WebBook
for detail
Original Measurements:
Ralston, A.W.; Hoerr, C.W.; Pool, W.O., J. Org. Chem. 8, 473-88 (1943).
Variables:
Temperature = 283 K to 336 K
Prepared By:
N. I. Lisov, V. P. Sazonov and N. V. Sazonov
Experimental Remarks:
The solubilities of N-phenyldecanamide (2) in nitroethane (1) in mass percent over the temperature range were presented in graphical form and in a table.
Experimental Data:
(Notes on the Nomenclature)
Solubility of N-phenyldecanamide (2) in nitroethane (1)
t/°C
T/K
10
2
* Mass Fraction w
2
(compiler)
g
2
/g
1
Mole Fraction x
2
(compiler)
10.0
283.2
12.3
14.0 x 10
2
0.041
16.7*
289.9
13.7
- x 10
0
0.046
30.0
303.2
17.9
21.8 x 10
2
0.062
33.8*
307.0
20.0
- x 10
0
0.071
41.3*
314.5
27.5
- x 10
0
0.103
43.8*
317.0
35.3
- x 10
0
0.142
50.0
323.2
57.1
133 x 10
2
0.288
50.4*
323.6
57.6
- x 10
0
0.292
59.3*
332.5
82.5
- x 10
0
0.589
62.7*
335.9
88.7
- x 10
0
0.704
Notes:
*
The compilers extracted these data from the published graphs.
Method/Apparatus/Procedure:
The synthetic method was used. The solubilities of (2) in (1) were determined in sealed tubes by the method and apparatus described in Ralston et al.
1
and Hoerr and Ralston.
2
Source and Purity of Materials:
(1) Source not specified; best grade reagent; dried and twice distilled.
(2) Obtained by heating of decanoic acid with redistilled aniline at (150 to 170)°C for 2 to 3 hours; purified by recrystallization; f. p. = 69.5°C.
Estimated Errors:
Temperature: control to ±0.2 K
References:
1
A. W. Ralston, C. W. Hoerr, and E. J. Hoffman, J. Am. Chem. Soc. 64, 1516 (1942).
2
C. W. Hoerr and A. W. Ralston, J. Am. Chem. Soc. 64, 2824 (1942).