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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Nitroethane with 1-Hexadecanol
Components:
(1) 1-Hexadecanol; C16H34O; [36653-82-4]
NIST Chemistry WebBook
for detail
(2) Nitroethane; C2H5NO2; [79-24-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Hoerr, C.W.; Harwood, H.J.; Ralston, A.W., J. Org. Chem. 9, 267-80 (1944).
Variables:
Temperature = 293 K to 319 K
Prepared By:
N. I. Lisov, V. P. Sazonov and N. V. Sazonov
Experimental Remarks:
The solubilities of 1-hexadecanol (2) in nitroethane (1) in mass percent over the temperature range were presented in graphical form and in a table.
Experimental Data:
(Notes on the Nomenclature)
Solubility of 1-hexadecanol (2) in nitroethane (1)
t/°C
T/K
10
2
* Mass Fraction w
2
(compiler)
g
2
/g
1
Mole Fraction x
2
(compiler)
20.0
293.2
0.1
0.1 x 10
2
0.0003
28.8*
302.0
1.2
- x 10
0
0.004
30.0
303.2
1.4
1.6 x 10
2
0.005
38.4*
311.6
9.1
- x 10
0
0.030
40.0
313.2
11.8
13.4 x 10
2
0.040
40.5*
313.7
13.0
- x 10
0
0.044
43.5*
316.7
25.9
- x 10
0
0.098
44.3*
317.5
38.2
- x 10
0
0.161
44.8*
318.0
63.9
- x 10
0
0.354
45.0*
318.2
77.0
- x 10
0
0.509
45.7*
318.9
85.7
- x 10
0
0.650
Notes:
*
The compilers extracted these data from the published graphs.
Method/Apparatus/Procedure:
The synthetic method was used. The solubility measurements were made with the equipment and in the manner described in Hoerr et al.
1
and Ralston et al.
2
Source and Purity of Materials:
(1) Source not specified; purity not specified.
(2) Source not specified; commercial product; purified by recrystallization; f. p. = 49.62°C.
Estimated Errors:
Solubility: Not specified.
Temperature: Not specified.
References:
1
C. W. Hoerr, E. F. Binkerd, W. O. Pool, and A. W. Ralston, J. Org. Chem. 9, 68 (1944).
2
A. W. Ralston, C. W. Hoerr, W. O. Pool, and H. J. Harwood, J. Org. Chem. 9, 102 (1944).