IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Acetonitrile with Alcohols
Components:
   (1) Acetonitrile; C2H3N; [75-05-8]  NIST Chemistry WebBook for detail
   (2) Alcohols; C10H22O and C12H26O; []  NIST Chemistry WebBook for detail
Original Measurements:
   Francis, A. W.; J. Phys. Chem. 60, 20 (1956).

 Variables:
   Temperature = 296 K to 308 K

 Prepared By:
   Valerii P. Sazonov and Nikolai V. Sazonov

 Experimental Data:   (Notes on the Nomenclature)
  
  Upper critical solution temperatures of the systems acetonitrile (1) + 1-alcohol (2)
t/°CT/KFinal Temperature (TFin)Chemical NameDensity ρ [(20 °C) g/L]
22.7295.96.81-Decanol; C10H22O; [112-30-1]831.8
35.2308.422.71-Dodecanol; C12H26O; [112-53-8]832/24 °C
 Method/Apparatus/Procedure:
   Observations were made after vigorous shaking in glass-stoppered graduated tubes of 15 mL capacity, immersed in water baths in large Dewar flasks. The water was agitated with a rapid stream of air bubbles. The temperature was adjusted by adding cooler or warmer water occasionally.

 Source and Purity of Materials:
   (1) Source not specified; purity not specified.
   (2) Source not specified; purified by crystallization.

 Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.