IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Acetonitrile with 1-Alkyl glyceryl ethers
Components:
   (1) 1-Alkyl glyceryl ethers; C13H28O3 - C24H50O3; []  NIST Chemistry WebBook for detail
   (2) Acetonitrile; C2H3N; [75-05-8]  NIST Chemistry WebBook for detail
Original Measurements:
   Schmid, H.H.O.; Mangold, H.K.; Lundberg, W.O.; Baumann, W.J., Microchem. J. 11, 306-14 (1966).

 Variables:
   Temperature = 295 K to 349 K

 Prepared By:
   Valerii P. Sazonov

 Experimental Data:   (Notes on the Nomenclature)
  
Upper critical solution temperatures of the binary systems acetonitrile (1) + alkyl glyceryl ether (2)
t/°CT/KChemical Name
21.5294.71-(cis,cis,cis-9,12,15-Octadecatrienoxy)-2,3-propanediol; C21H38O3;
25.5298.71-Decoxy-2,3-propanediol; C13H28O3;  [92219-12-0]
32.5305.71-Undecoxy-2,3-propanediol; C14H30O3; [126923-57-7]
33.5306.71-(cis,cis-9,12-Octadecadienoxy)-2,3-propanediol; C21H40O3; [70518-62-6]
38.0311.21-Dodecoxy-2,3-propanediol; C15H32O3;  [1561-07-5]
40.0313.21-(cis-9-Hexadecenoxy)-2,3-propanediol; C19H38O3;
43.5316.71-Tridecoxy-2,3-propanediol; C16H34O3; [126923-58-8]
48.0321.21-Tetradecoxy-2,3-propanediol; C17H36O3; [92219-13-1]
49.0322.21-(cis-9-Octadecenoxy)-2,3-propanediol; C21H42O3;  [2929-07-9] 
51.5324.71-(trans-9-Octadecenoxy)-2,3-propanediol; C21H42O3; [593-31-7]
53.0326.2.1-Pentadecoxy-2,3-propanediol; C18H38O3; [124770-96-3]
57.0330.21-Hexadecoxy-2,3-propanediol; C19H40O3;  [506-03-6]
61.0334.21-Heptadecoxy-2,3-propanediol; C20H42O3;  [113817-63-3]
65.0338.21-Octadecoxy-2,3-propanediol; C21H44O3;  [544-62-7]
68.5341.71-Nonadecoxy-2,3-propanediol; C22H46O3;  [10431-03-5]
72.0345.21-Eicosoxy-2,3-propanediol; C23H48O3; [158850-88-5]
76.0349.21-Heneicosoxy-2,3-propanediol; C24H50O3; [158789-24-3]
 Method/Apparatus/Procedure:
   A microscope equipped with a heating stage as in Schmid et al.1 was employed for determining UCST values. No experimental details are given.

 Source and Purity of Materials:
   (1) Baker Chemical Co.; reagent No. 9011.
   (2) Synthesized as in Baumann and Mangold.2

 Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.

 References:
   1. H. H. O. Schmid, H. K. Mangold, and W. O. Lundberg, J. Am. Oil Chem. Soc. 42, 372 (1965).
   2. W. J. Baumann and H. K. Mangold, J. Org. Chem. 29, 3055 (1964).