IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Acetonitrile with 1-Alkyl glyceryl ethers

   (1) 1-Alkyl glyceryl ethers; C13H28O3 - C24H50O3; []  NIST Chemistry WebBook for detail
   (2) Acetonitrile; C2H3N; [75-05-8]  NIST Chemistry WebBook for detail

Original Measurements:
   Schmid, H.H.O.; Mangold, H.K.; Lundberg, W.O.; Baumann, W.J., Microchem. J. 11, 306-14 (1966).

   Temperature = 295 K to 349 K

Prepared By:
   Valerii P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
Upper critical solution temperatures of the binary systems acetonitrile (1) + alkyl glyceryl ether (2)
t/°CT/KChemical Name
21.5294.71-(cis,cis,cis-9,12,15-Octadecatrienoxy)-2,3-propanediol; C21H38O3;
25.5298.71-Decoxy-2,3-propanediol; C13H28O3;  [92219-12-0]
32.5305.71-Undecoxy-2,3-propanediol; C14H30O3; [126923-57-7]
33.5306.71-(cis,cis-9,12-Octadecadienoxy)-2,3-propanediol; C21H40O3; [70518-62-6]
38.0311.21-Dodecoxy-2,3-propanediol; C15H32O3;  [1561-07-5]
40.0313.21-(cis-9-Hexadecenoxy)-2,3-propanediol; C19H38O3;
43.5316.71-Tridecoxy-2,3-propanediol; C16H34O3; [126923-58-8]
48.0321.21-Tetradecoxy-2,3-propanediol; C17H36O3; [92219-13-1]
49.0322.21-(cis-9-Octadecenoxy)-2,3-propanediol; C21H42O3;  [2929-07-9] 
51.5324.71-(trans-9-Octadecenoxy)-2,3-propanediol; C21H42O3; [593-31-7]
53.0326.2.1-Pentadecoxy-2,3-propanediol; C18H38O3; [124770-96-3]
57.0330.21-Hexadecoxy-2,3-propanediol; C19H40O3;  [506-03-6]
61.0334.21-Heptadecoxy-2,3-propanediol; C20H42O3;  [113817-63-3]
65.0338.21-Octadecoxy-2,3-propanediol; C21H44O3;  [544-62-7]
68.5341.71-Nonadecoxy-2,3-propanediol; C22H46O3;  [10431-03-5]
72.0345.21-Eicosoxy-2,3-propanediol; C23H48O3; [158850-88-5]
76.0349.21-Heneicosoxy-2,3-propanediol; C24H50O3; [158789-24-3]
   A microscope equipped with a heating stage as in Schmid et al.1 was employed for determining UCST values. No experimental details are given.

Source and Purity of Materials:
   (1) Baker Chemical Co.; reagent No. 9011.
   (2) Synthesized as in Baumann and Mangold.2

Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.

   1. H. H. O. Schmid, H. K. Mangold, and W. O. Lundberg, J. Am. Oil Chem. Soc. 42, 372 (1965).
   2. W. J. Baumann and H. K. Mangold, J. Org. Chem. 29, 3055 (1964).