IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Acetonitrile with 1,2-Dialkyl glyceryl ethers
Components:
   (1) 1,2-Dialkyl glyceryl ethers; C33H68O3 - C41H84O3; []  NIST Chemistry WebBook for detail
   (2) Acetonitrile; C2H3N; [75-05-8]  NIST Chemistry WebBook for detail
Original Measurements:
   Schmid, H.H.O.; Mangold, H.K.; Lundberg, W.O.; Baumann, W.J., Microchem. J. 11, 306-14 (1966).

 Variables:
   Temperature = 392 K to 430 K

 Prepared By:
   Valerii P. Sazonov

 Experimental Data:   (Notes on the Nomenclature)
  
Upper critical solution temperatures of the binary systems acetonitrile (1) + 1,2-dialkyl glyceryl ether (2)
t/°CT/KChemical Name
118.5391.72-(Dodecyloxy)-3-(octadecyloxy)-1-propanol; C33H68O3; [6076-36-4]
121.5394.72,3-Bis(9-octadecenyloxy)-(Z,Z)-1-propanol; C39H76O3; [6076-41-1]
129.5402.73-(Octadecyloxy)-2-(tetradecyloxy)-1-propanol; C35H72O3; [6076-37-5]
130.0403.22,3-Bis(hexadecyloxy)-1-propanol; C35H72O3; [6076-35-3]
135.5408.73-(Octadecyloxy)-2-(cis-9-octadecenyloxy)-1-propanol; C39H78O3;
135.5408.73-(cis-9-Octadecenyloxy)-2-(octadecyloxy)-1-propanol; C39H78O3;
138.5411.73-(Octadecyloxy)-2-(trans-9-octadecenyloxy)-1-propanol; C39H78O3;
140.5413.73-(Hexadecyloxy)-2-(octadecyloxy)-1-propanol; C37H76O3; [6110-57-2]
140.5413.72-(Hexadecyloxy)-3-(octadecyloxy)-1-propanol; C37H76O3; [6110-58-3]
148.5421.72,3-Bis(octadecyloxy)-1-propanol; C39H80O3; [6076-38-6]
156.5429.72-(Eicosyloxy)-3-(octadecyloxy)-1-propanol; C41H84O3; [6068-26-4]
 Method/Apparatus/Procedure:
   A microscope equipped with a heating stage as in Schmid et al.1 was employed for determining UCST values. No experimental details are given.

 Source and Purity of Materials:
   (1) Baker Chemical Co.; reagent No. 9011.
   (2) Synthesized as in work of Baumann and Mangold.2

 Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.

 References:
   1. H. H. O. Schmid, H. K. Mangold, and W. O. Lundberg, J. Am. Oil Chem. Soc. 42, 372 (1965).
   2. W. J. Baumann and H. K. Mangold, J. Org. Chem. 29, 3055 (1964).