IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Acetonitrile with 1,2,3-Trialkyl glyceryl ethers
Components:
   (1) 1,2,3-Trialkyl glyceryl ethers; C47H96O3 - C57H116O3; []  NIST Chemistry WebBook for detail
   (2) Acetonitrile; C2H3N; [75-05-8]  NIST Chemistry WebBook for detail
Original Measurements:
   Schmid, H.H.O.; Mangold, H.K.; Lundberg, W.O.; Baumann, W.J., Microchem. J. 11, 306-14 (1966).

 Variables:
   Temperature = 464 K to 495 K

 Prepared By:
   Valerii P. Sazonov

 Experimental Data:   (Notes on the Nomenclature)
  
Upper critical solution temperatures of the binary systems acetonitrile (1) + 1,2,3-trialkyl glyceryl ether (2)
t/°CT/KChemical Name
191.0464.21-(Dodecyloxy)-2,3-bis(hexadecyloxy)propane; C47H96O3; [6076-43-3]
196.5469.7(Z,Z,Z)-1,2,3-Tris(9-octadecenyloxy)propane; C57H110O3; [10431-15-9]
198.0471.21-(Dodecyloxy)-2-(hexadecyloxy)-3-(octadecyloxy)propane; C49H100O3; [6068-27-5]
204.5477.71-(Dodecyloxy)-2,3-bis(octadecyloxy)propane; C51H104O3; [5896-48-0]
204.5477.71,2,3-Tris(hexadecyloxy)propane; C51H104O3; [6110-59-4]
206.0479.2(Z,Z)-1,2-Bis(9-octadecenyloxy)-3-(octadecyloxy)propane; C57H112O3; [10431-14-8]
213.5486.7(Z)-1-(9-Octadecenyloxy)-2,3-bis(octadecyloxy)propane; C57H114O3; [13166-06-8]
222.0495.21,2,3-Tris(octadecyloxy)propane; C57H116O3; [6076-42-2]
 Method/Apparatus/Procedure:
   A microscope equipped with a heating stage as in Schmid et al.1 was employed for determining UCST values. No experimental details are given.

 Source and Purity of Materials:
   (1) Baker Chemical Co.; reagent No. 9011.
   (2) Synthesized as in work of Baumann and Mangold.2

 Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.

 References:
   1. H. H. O. Schmid, H. K. Mangold, and W. O. Lundberg, J. Am. Oil Chem. Soc. 42, 372 (1965).
   2. W. J. Baumann and H. K. Mangold, J. Org. Chem. 29, 3055 (1964).