IUPAC-NIST Solubilities Database

IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Solubility System: Acetonitrile with Hexanedioic acid

Components:
   (1) Hexanedioic acid; C6H10O4; [124-04-9]  NIST Chemistry WebBook for detail
   (2) Acetonitrile; C2H3N; [75-05-8]  NIST Chemistry WebBook for detail

Evaluator:
   Valerii P. Sazonov, Technical University, Samara, Russia, July, 2001

Critical Evaluation:

           Solubilities in the system comprising acetonitrile (1) and hexanedioic acid (2) have been reported in two publications over a very limited range of temperatures. No data appear to have been reported for the solubility of (1) in (2). Smolyan et al.¹ determined solubility of hexanedioic acid in acetonitrile at 298 K and 323 K. Smagowski² carried out measurements of the solubility of (2) in (1) between 273 K and 308 K by the titration method.
        At the one temperature (298 K) where comparison is possible, the two studies are in poor agreement. Accordingly, all the available data (see the relevant data sheets) must be regarded as doubtful.
        Solubilities in the system comprising acetonitrile (1) and hexanedioic acid (2) have been reported in two publications over a very limited range of temperatures. No data appear to have been reported for the solubility of (1) in (2). Smolyan et al.¹ determined solubility of hexanedioic acid in acetonitrile at 298 and 323 K. Smagowski² carried out measurements of the solubility of (2) in (1) between 273 and 308 K by the titration method.
        At the one temperature (298 K) where comparison is possible, the two studies are in poor agreement. Accordingly, all the available data (see the relevant data sheets) must be regarded as doubtful.

Experimental Data:   (Notes on the Nomenclature)

References: (Click a link to see its experimental data associated with the reference)

   1  Smolyan, Z.S.; Matveeva, G.N.; Fukin, V.K.; Korotaevskii, K.N.; Ignat'eva, A.P.; Kornilina, A.N.; Zvereva, L.S.; Fomin, A.S., Khim. Prom-st (Moscow) 48, 508 (1972).
   2  Smagowski, H., Zesz. Nauk. Wydz. Mat., Fiz. Chem., Univ. Gdanski, Chem. 3, 45 (1974).