IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Acetonitrile with Carbon disulfide
Components:
   (1) Acetonitrile; C2H3N; [75-05-8]  NIST Chemistry WebBook for detail
   (2) Carbon disulfide; CS2; [75-15-0]  NIST Chemistry WebBook for detail
Original Measurements:
   Poppe, G., Bull. Soc. Chim. Belg. 44, 640 (1935).

 Variables:
   Temperature = 324 K
   Pressure = 582-9803

 Prepared By:
   Valerii P. Sazonov

 Experimental Remarks:
   The upper critical solution temperature (UCST) was reported to be 50.90 °C (324.05 K, compiler). The value of dTc/dP was reported to be 0.0197 K·kPa-1 in the pressure range 582 kPa to 9803 kPa.

 Experimental Data:   (Notes on the Nomenclature)
   Method/Apparatus/Procedure:
   The synthetic method was used. Observations were carried out in sealed tubes in the presence of the vapor phase. A Cailletet tube with a Kuenen electromagnetic stirrer was used in the experiments at higher pressure. A thermostating cylinder was also used to control the temperature.

 Source and Purity of Materials:
   (1) Obtained from the Bureau Etalons Physico-Chimiques.
   (2) Obtained from the Bureau Etalons Physico-Chimiques.

 Estimated Errors:

   Pressure: ± 100 kPa.