IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Acetonitrile with Decanamine
Components:
   (1) Decanamine; C10H23N; [2016-57-1]  NIST Chemistry WebBook for detail
   (2) Acetonitrile; C2H3N; [75-05-8]  NIST Chemistry WebBook for detail
Original Measurements:
   Ralston, A.W.; Hoerr, C.W.; Pool, W.O.; Harwood, H.J., J. Org. Chem. 9, 102-112 (1944).

 Variables:
   Temperature = 253 K to 286 K

 Prepared By:
   Valerii P. Sazonov and Nikolai V. Sazonov

 Experimental Remarks:
   The solubilities of decanamine (2) in acetonitrile (1) in mass percent over the indicated temperature range were reported in graphical form and in a table.

 Experimental Data:   (Notes on the Nomenclature)
  
Solubility of decanamine (2) in acetonitrile (1)
t/°CT/Kg2/100 g solution102 * Mass Fraction w2 (compiler)Mole Fraction x2 (compiler)
-20.0253.22.82.70.007
-15.0*258.2-3.80.010
-5.5*267.7-7.50.021
0.0273.212.711.30.032
1.4*274.6-11.40.033
6.4*279.6-23.40.074
8.0*281.2-35.80.127
9.0*282.2-48.80.199
10.0*283.2-68.60.363
10.9*284.1-80.70.522
13.2*286.4-90.50.713
 Notes:
   *  The compilers extracted these data from the published graphs.

 Method/Apparatus/Procedure:
   The solubility measurements were made with the equipment and in the manner previously described elsewhere.1,2

 Source and Purity of Materials:
   (1) Source not specified; purity not specified; freshly distilled and cooled without access to the atmosphere, to prevent contamination with carbon dioxide.
   (2) Prepared by hydrogenation of the highly purified nitrile as in work1; purified by two vacuum distillations; freezing point = 16.11 °C

 Estimated Errors:
   Solubility: Not specified
   Temperature: Not specified

 References:
   1. C. W. Hoerr, E. F. Binkerd, W. O. Pool, and A. W. Ralston, J. Org. Chem. 9, 68 (1944)
   2. A. W. Ralston, C. W. Hoerr, and E. J. Hoffman, J. Am. Chem. Soc. 64, 1516 (1942).