IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Acetonitrile with Tetradecanamine
Components:
   (1) Acetonitrile; C2H3N; [75-05-8]  NIST Chemistry WebBook for detail
   (2) Tetradecanamine; C14H31N; [2016-42-4]  NIST Chemistry WebBook for detail
Original Measurements:
   Ralston, A.W.; Hoerr, C.W.; Pool, W.O.; Harwood, H.J., J. Org. Chem. 9, 102-112 (1944).

 Variables:
   Temperature = 290 K to 308 K

 Prepared By:
   Valerii P. Sazonov and Nikolai V. Sazonov

 Experimental Remarks:
   The solubilities of tetradecanamine (2) in acetonitrile (1) in mass percent over the indicated temperature range were reported in graphical form and in a table.

 Experimental Data:   (Notes on the Nomenclature)
  
Solubility of tetradecanamine (2) in acetonitrile (1)
t/°CT/Kg2/100 g solution102 * Mass Fraction w2 (compiler)Mole Fraction x2 (compiler)
16.7*289.9-1.30.003
20.0293.21.81.80.004
25.4*298.6-5.40.011
30.0303.214.913.00.028
32.0*305.2-24.00.057
32.4*305.6-44.90.136
33.0*306.2-63.90.254
33.6*306.8-77.40.397
35.0*308.2-88.60.599
 Notes:
   *  The compiler extracted these data from the published graphs.

 Method/Apparatus/Procedure:
   The solubility measurements were made with the equipment and in the manner previously described elsewhere.1,2

 Source and Purity of Materials:
   (1) Source not specified; purity not specified; freshly distilled and cooled without access to the atmosphere, to prevent contamination with carbon dioxide.
   (2) Prepared by hydrogenation of the highly purified nitrile as in work1; purified by two vacuum distillations; freezing point = 38.19 °C

 Estimated Errors:
   Solubility: Not specified
   Temperature: Not specified

 References:
   1. C. W. Hoerr, E. F. Binkerd, W. O. Pool, and A. W. Ralston, J. Org. Chem. 9, 68 (1944)
   2. A. W. Ralston, C. W. Hoerr, and E. J. Hoffman, J. Am. Chem. Soc. 64, 1516 (1942).