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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Acetonitrile with Hexane
Components:
(1) Hexane; C6H14; [110-54-3]
NIST Chemistry WebBook
for detail
(2) Acetonitrile; C2H3N; [75-05-8]
NIST Chemistry WebBook
for detail
Original Measurements:
Rakotondramanana, S.; Borredon, M.E.; Mollnier, J., J. Chem. Eng. Data 32, 308-11 (1987).
Variables:
Temperature = 293 K and 303 K
Prepared By:
Valerii P. Sazonov and Nikolai V. Sazonov
Experimental Data:
(Notes on the Nomenclature)
Mutual solubility of acetonitrile (1) and hexane (2)
t/°C
T/K
10
2
* Mass Fraction w
1
Mole Fraction x
1
(compiler)
Comment(s)
20.0
293.2
2.9
0.059
Hydrocarbon-rich phase
30.0
303.2
3.8
0.077
Hydrocarbon-rich phase
20.0
293.2
90.1
0.950
Acetonitrile-rich phase
30.0
303.2
85.1
0.923
Acetonitrile-rich phase
Method/Apparatus/Procedure:
The titration method was used. No experimental details were reported.
Source and Purity of Materials:
(1) Source not specified; commercial product; minimum purity of 99 mass %; dried with a 4 A molecular sieve.
(2) Source not specified; commercial product; minimum purity of 99 mass %.
Estimated Errors:
Temperature: ± 0.5 K.