IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Acetonitrile with 1-Heptene

   (1) 1-Heptene; C7H14; [592-76-7]  NIST Chemistry WebBook for detail
   (2) Acetonitrile; C2H3N; [75-05-8]  NIST Chemistry WebBook for detail

Original Measurements:
   Kikic I.; Alessi, P., Ann. Chim. (Rome) 64, 363 (1974).

   Temperature = 291 K

Prepared By:
   Valerii P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
Mutual solubility of acetonitrile (1) and 1-heptene (2)
t/°CT/K102 * Mass Fraction w1 (compiler) Mole Fraction x1Comment(s)
18.0291.28.460.181Hydrocarbon-rich phase
18.0291.274.20.873Acetonitrile-rich phase
   The analytical method was used. A sample of each phase was withdrawn with a syringe and immediately analyzed by GLC. No experimental details given.

Source and Purity of Materials:
   (1) 3M Minnesota; used without any preliminary treatment, since the analysis by GLC did not indicate any detectable impurity.
   (2) Fluka; 99.9 mole percent minimum purity; not purified.

Estimated Errors:

   Temperature: ± 0.1 K.