IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Fluorobenzene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Fluorobenzene; C6H5F; [462-06-6]  NIST Chemistry WebBook for detail
Original Measurements:
   Andrews, L.J.; Keefer, R.M., J. Am. Chem. Soc. 1950, 72(7), 3113-6.

 Variables:
   Temperature = One temperature

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°Cg1/V2 [g dm**-3]102 * Concentration c1 [mol dm**-3]Concent. c1 Note104 * Mole Fraction x1x1 Note
251.551.613b2.918c
 Notes:
   a  Reported.
   b  Calculated by F. W. Getzen.
   c  Calculated by compiler.

 Method/Apparatus/Procedure:
   The water was saturated with fluorobenzenein a glass-stoppered Erlenmeyer flask rotated in a constant temperature bath for 20 hours. The saturated solution was extracted with n-hexane. The optical density of the extract was measured against a standard n-hexane blank with a Beckman spectrophotometer (1).

 Source and Purity of Materials:
   (1) Eastman Kodak Co., commercial reagent, b.p 84.4°C, fractionated before use.
   (2) Not specified.

 Estimated Errors:
   Solubility: ± 10% (compiler).
   Temperature: ± 0.1 K (compiler).

 References:
   1Andrews, L. J.; Keefer, R. M. J. Am. Chem. Soc. 1949, 71(11), 3644-7.