IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Cyclohexene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Cyclohexene; C6H10; [110-83-8]  NIST Chemistry WebBook for detail
Original Measurements:
   Pierotti, R.A.; Liabastre, A.A., "Structure and properties of water solutions." U.S. Nat. Tech. Inform. Serv., PB Rep., 1972, No. 21163, 113 p.

 Variables:
   Temperature = 278.26-318.36 K

 Prepared By:
   M.C. Haulait-Pirson

 Experimental Remarks:
   The solubility of cyclohexene in water at 20°C was reported to be x1 = 5 x 10-5.
The corresponding mass percent calculated by the compiler is 0.023 g(1)/100 g sln.

The solubility of water in cyclohexene at 20 °C was reported to be x2 = 0.0019.
The corresponding mass percent calculated by the compiler is 0.042 g(2)/100 g sln.

 Experimental Data:   (Notes on the Nomenclature)
  
Solubility of cyclohexene in water
T/Kg2/100 g solution103 * Mole Fraction x1
278.260.02800 ± 0.000690.06141
288.360.02985 ± 0.000610.06546
298.260.02990 ± 0.000820.06557
308.360.03025 ± 0.000700.06634
318.360.03105 ± 0.000930.06809
 Method/Apparatus/Procedure:
   10 mL of (2) were placed along with 4-10 drops (1) in 10 mL serum bottles, which were then tightly capped, and placed in the rotating basket and rotated for 24 hours. The bottles were then hand shaken to remove (1) droplets from the stoppers and then replaced in the bath with tops down for an additional 24 hours. The solute concentrations were determined by use of a flame-ionization gas chromatograph. Many details about equipment, operating conditions and calculation are given in the paper.

 Source and Purity of Materials:
   (1) Eastman Organic Chemicals, No. 1043; washed with water to remove stabilizing agent.
   (2) laboratory distilled water

 Estimated Errors:
   Solubility: standard deviation from at least 15 measurements are given above.