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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Cumene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Cumene; C9H12; [98-82-8]
NIST Chemistry WebBook
for detail
Original Measurements:
McAuliffe, C., Nature (London) 1963, 200, 1092-3.
Variables:
Temperature = 25 °C
Prepared By:
A. Maczynski and Z. Maczynska
Experimental Remarks:
The solubility of cumene in water at 25°C was reported to be 0.0053 g(1)/100 g sln.
The corresponding mole fraction,
x
1
, calculated by the compilers is 7.9 × 10
6
.
Experimental Data:
(Notes on the Nomenclature)
Method/Apparatus/Procedure:
The saturated solution of (1) in (2) was prepared by either shaking vigourously on a reciprocal shaker or stirring for several days with a magnetic stirrer.
A 0.05 mL or 0.10 mL sample of the hydrocarbon-saturated water was injected directly into a gas liquid chromatograph.
Source and Purity of Materials:
(1) Phillips Petroleum Co.; 99+%; used as received.
(2) distilled.
Estimated Errors:
Solubility: 0.0005 (standard deviation of mean)
Temperature: ± 1.5°C