IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Decane with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Decane; C10H22; [124-18-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Franks, F., Nature (London) 1966, 210, 87-8.

Variables:
   Temperature = 25 °C

Prepared By:
   F. Kapuku

Experimental Remarks:

   The solubility of decane in water at 25°C was reported to be in mole fraction x1 = 2.5 × 10–9.

The corresponding mass percent calculated by the compiler is 1.98 × 10–6 g(1)/100 g sln.

Experimental Data:   (Notes on the Nomenclature)
   Method/Apparatus/Procedure:
   The analysis was performed by gas liquid chromatography. After equilibrating the (1)/(2) mixtures in a thermostat, up to 0.5 ml of the aqueous phase was injected into the fractionator column, and (2) was removed by "Drierite". The (1) concentrations were obtained from the peak areas, after initial calibrations.

Source and Purity of Materials:
   (1) Fluka; purum grade; purity > 97% (chromatographic analysis).
   (2) not specified.

Estimated Errors:
   Solubility: ± 12%