IUPAC-NIST Solubilities Database

IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Solubility System: Ethene with 2-Propanone (acetone)

Components:
   (1) 2-Propanone (acetone); C3H6O; [67-64-1]  NIST Chemistry WebBook for detail
   (2) Ethene; C2H4; [74-85-1]  NIST Chemistry WebBook for detail

Original Measurements:
   Kiss, G.; Vanko, M.; Hagara, A.; Vanko, A., Petrochemia (Czechoslovakia), 1980, 20, 132-137.

Variables:
   Temperature = 238.15 K, 248.15 K
   Pressure = 0.101 to 1.013 MPa

Prepared By:
   W. Hayduk

Experimental Remarks:

   Mole fraction ethylene at a gas partial pressure of 1 atm and 238.15 K is x₁= 0.0333 as estimated by compiler assuming Henry's law.

Mole fraction ethylene at a gas partial pressure of 1 atm and 248.15 K is x₁= 0.0256 as estimated by compiler assuming Henry's law.

Experimental Data:   (Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)


t/°C	T/K	Pressure [MPa]	Henry's law constant, K [atm(mole fraction)^–1]	Henry Constant Note	Mole Fraction (x₁)	x₁ Note	Solubility [cm³ gas at NTP (g solvent)⁻¹]	Remark(s)
−35.0	238.15	0.152	30.33	1	0.0495	1	20.08	By method A:
−35.0	238.15	0.203	30.36	1	0.0659	1	27.21	By method A:
−35.0	238.15	0.304	30.32	1	0.0990	1	42.38	By method A:
−35.0	238.15	0.405	30.36	1	0.1318	1	58.55	By method A:
−35.0	238.15	0.507	30.00	1	0.1667	1	77.21	By method A:
−35.0	238.15	0.608	28.97	1	0.2071	1	100.80	By method A:
−35.0	238.15	0.709	28.30	1	0.2474	1	126.85	By method A:
−35.0	238.15	0.811	26.50	1	0.3019	1	166.87	By method A:
−35.0	238.15	0.912	26.55	1	0.3390	1	197.88	By method A:
−35.0	238.15	1.013	25.89	1	0.3863	1	242.87	By method A:
−35.0	238.15	0.101	33.70	1	0.0297	1	11.8	By method B:
−35.0	238.15	0.203	33.12	1	0.0604	1	24.8	By method B:
−35.0	238.15	0.405	30.48	1	0.1313	1	58.3	By method B:
−25.0	248.15	0.152	39.09	1	0.0384	1	15.40	By method A:
−25.0	248.15	0.203	37.40	1	0.0535	1	21.80	By method A:
−25.0	248.15	0.304	38.95	1	0.0770	1	32.20	By method A:
−25.0	248.15	0.405	38.63	1	0.1035	1	44.57	By method A:
−25.0	248.15	0.507	30.05	1	0.1280	1	56.66	By method A:
−25.0	248.15	0.608	36.83	1	0.1629	1	75.11	By method A:
−25.0	248.15	0.709	37.53	1	0.1865	1	88.48	By method A:
−25.0	248.15	0.811	35.89	1	0.2229	1	110.69	By method A:
−25.0	248.15	0.912	36.68	1	0.2454	1	125.49	By method A:
−25.0	248.15	1.013	35.10	1	0.2849	1	153.73	By method A:
−25.0	248.15	0.101	41.20	1	0.0243	1	9.6	By method B:
−25.0	248.15	0.203	41.18	1	0.0486	1	19.7	By method B:
−25.0	248.15	0.405	39.57	1	0.1011	1	43.4	By method B:

Notes:
¹ Calculated by compiler.

Method/Apparatus/Procedure:
Method A: The solubility cell is placed in a metal block surrounded by a cooling coil supplied by liquid nitrogen. Septum stoppers at the top and bottom permit sampling of the solution by means of a pressure microsyringe. The cell is initially charged with 2.5 cm³ of solvent which is then saturated with gas by bubbling through a distribution ring containing 0.1 mm holes. The gas is continuously released through a pressure controlling manometer. The temperature is measured by miniature thermocouple. Analysis is by gas chromatography.

Method B: Apart from the explanation that a static method was used, no further description is provided.

Source and Purity of Materials:
   No information about the source and purity of gas or solvent is provided.

Estimated Errors:
   Solubility: δ s/s = ± 0.02 (Compiler)
   Temperature: δTK = ± 0.1
   Pressure: δp/MPa = ± 0.001