IUPAC-NIST Solubilities Database

IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Solubility System: Ethene with 2-Propanone (acetone)

Components:
   (1) 2-Propanone (acetone); C3H6O; [67-64-1]  NIST Chemistry WebBook for detail
   (2) Ethene; C2H4; [74-85-1]  NIST Chemistry WebBook for detail

Original Measurements:
   Voronkov, A.P.; Mislavskaya, V.S.; Mushii, R. Ya.; Drygina, V.V., Zh. Prikl. Khim. 1979, 52, 2642; VINITI No. 458-79.

Variables:
   Temperature = 263.15 K to 373.15 K
   Pressure = 0.101 to 7.60 MPa

Prepared By:
   W. Hayduk

Experimental Remarks:

   Henry's law is obeyed up to about 25 atm (2.53 MPa). The data were from the paper deposited in VINITI, Moscow.

Experimental Data:   (Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)

Mole Fractions
t/°C	T/K	Pressure [atm]	Pressure Note	Pressure [atm]	Pressure Note	Mole Fraction (x₁)	x₁ Note	Mole Fraction of Gas (y₁)	y₁ Note
−10	263.15	0.9494	1	1	Total Pressure, P	0.990	Acetone in Liquid, 1	0.606	Acetone in Gas, 1
−10	263.15	0.9494	1	1	Total Pressure, P	0.010	1 Ethene in Liquid	0.9494	Ethene in Gas
−10	263.15	2.95	1	3	Total Pressure, P	0.976	Acetone in Liquid, 1	0.0180	Acetone in Gas, 1
−10	263.15	2.95	1	3	Total Pressure, P	0.024	1 Ethene in Liquid	0.9820	Ethene in Gas
−10	263.15	4.95	1	5	Total Pressure, P	0.960	Acetone in Liquid, 1	0.0101	Acetone in Gas, 1
−10	263.15	4.95	1	5	Total Pressure, P	0.040	1 Ethene in Liquid	0.9899	Ethene in Gas
−10	263.15	19.96	1	20	Total Pressure, P	0.844	Acetone in Liquid, 1	0.0021	Acetone in Gas, 1
−10	263.15	9.95	1	10	Total Pressure, P	0.078	1 Ethene in Liquid	0.9952	Ethene in Gas
−10	263.15	9.95	1	10	Total Pressure, P	0.922	Acetone in Liquid, 1	0.0048	Acetone in Gas, 1
−10	263.15	14.95	1	15	Total Pressure, P	0.122	1 Ethene in Liquid	0.9968	Ethene in Gas
−10	263.15	14.95	1	15	Total Pressure, P	0.878	Acetone in Liquid, 1	0.0032	Acetone in Gas, 1
−10	263.15	19.96	1	20	Total Pressure, P	0.156	1 Ethene in Liquid	0.9979	Ethene in Gas
−10	263.15	24.96	1	25	Total Pressure, P	0.786	Acetone in Liquid, 1	0.0014	Acetone in Gas, 1
−10	263.15	24.96	1	25	Total Pressure, P	0.214	1 Ethene in Liquid	0.9986	Ethene in Gas
−10	263.15	29.97	1	30	Total Pressure, P	0.680	Acetone in Liquid, 1	0.0009	Acetone in Gas, 1
−10	263.15	29.97	1	30	Total Pressure, P	0.320	1 Ethene in Liquid	0.9991	Ethene in Gas
10	283.15	0.6017	1	1	Total Pressure, P	0.995	Acetone in Liquid, 1	0.3983	Acetone in Gas, 1
10	283.15	0.0617	1	1	Total Pressure, P	0.005	1 Ethene in Liquid	0.6017	Ethene in Gas
10	283.15	2.77	1	3	Total Pressure, P	0.984	Acetone in Liquid, 1	0.0765	Acetone in Gas, 1
10	283.15	2.77	1	3	Total Pressure, P	0.016	1 Ethene in Liquid	0.9235	Ethene in Gas
10	283.15	4.81	1	5	Total Pressure, P	0.973	Acetone in Liquid, 1	0.0385	Acetone in Gas, 1
10	283.15	4.81	1	5	Total Pressure, P	0.027	1 Ethene in Liquid	0.9616	Ethene in Gas
10	283.15	9.84	1	10	Total Pressure, P	0.953	Acetone in Liquid, 1	0.0157	Acetone in Gas, 1
10	283.15	9.84	1	10	Total Pressure, P	0.047	1 Ethene in Liquid	0.9843	Ethene in Gas
10	283.15	14.85	1	15	Total Pressure, P	0.934	Acetone in Liquid, 1	0.0102	Acetone in Gas, 1
10	283.15	14.85	1	15	Total Pressure, P	0.066	1 Ethene in Liquid	0.9898	Ethene in Gas
10	283.15	19.86	1	20	Total Pressure, P	0.914	Acetone in Liquid, 1	0.0070	Acetone in Gas, 1
10	283.15	19.86	1	20	Total Pressure, P	0.086	1 Ethene in Liquid	0.9930	Ethene in Gas
10	283.15	24.87	1	25	Total Pressure, P	0.898	Acetone in Liquid, 1	0.0053	Acetone in Gas, 1
10	283.15	24.87	1	25	Total Pressure, P	0.102	1 Ethene in Liquid	0.9947	Ethene in Gas
10	283.15	29.87	1	30	Total Pressure, P	0.870	Acetone in Liquid, 1	0.0043	Acetone in Gas, 1
10	283.15	29.87	1	30	Total Pressure, P	0.130	1 Ethene in Liquid	0.9957	Ethene in Gas
10	283.15	34.87	1	35	Total Pressure, P	0.822	Acetone in Liquid, 1	0.0037	Acetone in Gas, 1
10	283.15	34.87	1	35	Total Pressure, P	0.178	1 Ethene in Liquid	0.9963	Ethene in Gas
30	303.15	0.576	1	1	Total Pressure, P	0.997	Acetone in Liquid, 1	0.4240	Acetone in Gas, 1
30	303.15	0.576	1	1	Total Pressure, P	0.003	1 Ethene in Liquid	0.5760	Ethene in Gas
30	303.15	2.78	1	3	Total Pressure, P	0.984	Acetone in Liquid, 1	0.0744	Acetone in Gas, 1
30	303.15	2.78	1	3	Total Pressure, P	0.016	1 Ethene in Liquid	0.9256	Ethene in Gas
30	303.15	4.80	1	5	Total Pressure, P	0.978	Acetone in Liquid, 1	0.0410	Acetone in Gas, 1
30	303.15	4.80	1	5	Total Pressure, P	0.022	1 Ethene in Liquid	0.9590	Ethene in Gas
30	303.15	9.81	1	10	Total Pressure, P	0.960	Acetone in Liquid, 1	0.0194	Acetone in Gas, 1
30	303.15	9.81	1	10	Total Pressure, P	0.040	1 Ethene in Liquid	0.9806	Ethene in Gas
30	303.15	14.83	1	15	Total Pressure, P	0.946	Acetone in Liquid, 1	0.0115	Acetone in Gas, 1
30	303.15	14.83	1	15	Total Pressure, P	0.054	1 Ethene in Liquid	0.9885	Ethene in Gas
30	303.15	19.81	1	20	Total Pressure, P	0.924	Acetone in Liquid, 1	0.0096	Acetone in Gas, 1
30	303.15	19.81	1	20	Total Pressure, P	0.076	1 Ethene in Liquid	0.9904	Ethene in Gas
30	303.15	24.81	1	25	Total Pressure, P	0.896	Acetone in Liquid, 1	0.0078	Acetone in Gas, 1
30	303.15	24.81	1	25	Total Pressure, P	0.104	1 Ethene in Liquid	0.9922	Ethene in Gas
30	303.15	29.81	1	30	Total Pressure, P	0.878	Acetone in Liquid, 1	0.0064	Acetone in Gas, 1
30	303.15	29.81	1	30	Total Pressure, P	0.122	1 Ethene in Liquid	0.9936	Ethene in Gas
30	303.15	34.80	1	35	Total Pressure, P	0.854	Acetone in Liquid, 1	0.0056	Acetone in Gas, 1
30	303.15	34.80	1	35	Total Pressure, P	0.146	1 Ethene in Liquid	0.9944	Ethene in Gas
30	303.15	39.81	1	40	Total Pressure, P	0.824	Acetone in Liquid, 1	0.0048	Acetone in Gas, 1
30	303.15	39.81	1	40	Total Pressure, P	0.176	1 Ethene in Liquid	0.9952	Ethene in Gas
30	303.15	44.82	1	45	Total Pressure, P	0.794	Acetone in Liquid, 1	0.0040	Acetone in Gas, 1
30	303.15	44.82	1	45	Total Pressure, P	0.206	1 Ethene in Liquid	0.9960	Ethene in Gas
30	303.15	49.82	1	50	Total Pressure, P	0.764	Acetone in Liquid, 1	0.0036	Acetone in Gas, 1
30	303.15	49.82	1	50	Total Pressure, P	0.236	1 Ethene in Liquid	0.9964	Ethene in Gas
50	323.15	2.54	1	3	Total Pressure, P	0.993	Acetone in Liquid, 1	0.1518	Acetone in Gas, 1
50	323.15	2.54	1	3	Total Pressure, P	0.007	1 Ethene in Liquid	0.8482	Ethene in Gas
50	323.15	4.57	1	5	Total Pressure, P	0.985	Acetone in Liquid, 1	0.0867	Acetone in Gas, 1
50	323.15	4.57	1	5	Total Pressure, P	0.015	1 Ethene in Liquid	0.9133	Ethene in Gas
50	323.15	9.58	1	10	Total Pressure, P	0.968	Acetone in Liquid, 1	0.0421	Acetone in Gas, 1
50	323.15	9.58	1	10	Total Pressure, P	0.032	1 Ethene in Liquid	0.9579	Ethene in Gas
50	323.15	14.58	1	15	Total Pressure, P	0.951	Acetone in Liquid, 1	0.0280	Acetone in Gas, 1
50	323.15	14.58	1	15	Total Pressure, P	0.049	1 Ethene in Liquid	0.9720	Ethene in Gas
50	323.15	19.58	1	20	Total Pressure, P	0.930	Acetone in Liquid, 1	0.0212	Acetone in Gas, 1
50	323.15	19.58	1	20	Total Pressure, P	0.070	1 Ethene in Liquid	0.9831	Ethene in Gas
50	323.15	24.58	1	25	Total Pressure, P	0.914	Acetone in Liquid, 1	0.0169	Acetone in Gas, 1
50	323.15	24.58	1	25	Total Pressure, P	0.086	1 Ethene in Liquid	0.9880	Ethene in Gas
50	323.15	29.58	1	30	Total Pressure, P	0.896	Acetone in Liquid, 1	0.0140	Acetone in Gas, 1
50	323.15	29.58	1	30	Total Pressure, P	0.104	1 Ethene in Liquid	0.9860	Ethene in Gas
50	323.15	34.58	1	35	Total Pressure, P	0.872	Acetone in Liquid, 1	0.0120	Acetone in Gas, 1
50	323.15	34.58	1	35	Total Pressure, P	0.128	1 Ethene in Liquid	0.9880	Ethene in Gas
50	323.15	39.58	1	40	Total Pressure, P	0.858	Acetone in Liquid, 1	0.0106	Acetone in Gas, 1
50	323.15	39.58	1	40	Total Pressure, P	0.142	1 Ethene in Liquid	0.9894	Ethene in Gas
50	323.15	44.57	1	45	Total Pressure, P	0.832	Acetone in Liquid, 1	0.0096	Acetone in Gas, 1
50	323.15	44.57	1	45	Total Pressure, P	0.168	1 Ethene in Liquid	0.9904	Ethene in Gas
50	323.15	49.57	1	50	Total Pressure, P	0.812	Acetone in Liquid, 1	0.0087	Acetone in Gas, 1
50	323.15	49.57	1	50	Total Pressure, P	0.188	1 Ethene in Liquid	0.9913	Ethene in Gas
50	323.15	54.56	1	55	Total Pressure, P	0.788	Acetone in Liquid, 1	0.0080	Acetone in Gas, 1
50	323.15	54.56	1	55	Total Pressure, P	0.212	1 Ethene in Liquid	0.9920	Ethene in Gas
50	323.15	59.56	1	60	Total Pressure, P	0.764	Acetone in Liquid, 1	0.0074	Acetone in Gas, 1
50	323.15	59.56	1	60	Total Pressure, P	0.236	1 Ethene in Liquid	0.9926	Ethene in Gas
80	353.15	3.51	1	5	Total Pressure, P	0.988	Acetone in Liquid, 1	0.2971	Acetone in Gas, 1
80	353.15	3.51	1	5	Total Pressure, P	0.012	1 Ethene in Liquid	0.7029	Ethene in Gas
80	353.15	8.66	1	10	Total Pressure, P	0.974	Acetone in Liquid, 1	0.1339	Acetone in Gas, 1
80	353.15	8.66	1	10	Total Pressure, P	0.026	1 Ethene in Liquid	0.8661	Ethene in Gas
80	353.15	13.67	1	15	Total Pressure, P	0.956	Acetone in Liquid, 1	0.0890	Acetone in Gas, 1
80	353.15	13.67	1	15	Total Pressure, P	0.044	1 Ethene in Liquid	0.9110	Ethene in Gas
80	353.15	18.69	1	20	Total Pressure, P	0.940	Acetone in Liquid, 1	0.0653	Acetone in Gas, 1
80	353.15	18.69	1	20	Total Pressure, P	0.060	1 Ethene in Liquid	0.9347	Ethene in Gas
80	353.15	23.67	1	25	Total Pressure, P	0.920	Acetone in Liquid, 1	0.0532	Acetone in Gas, 1
80	353.15	23.67	1	25	Total Pressure, P	0.080	1 Ethene in Liquid	0.9468	Ethene in Gas
80	353.15	28.68	1	30	Total Pressure, P	0.904	Acetone in Liquid, 1	0.0440	Acetone in Gas, 1
80	353.15	28.68	1	30	Total Pressure, P	0.096	1 Ethene in Liquid	0.9560	Ethene in Gas
80	353.15	33.67	1	35	Total Pressure, P	0.886	Acetone in Liquid, 1	0.0379	Acetone in Gas, 1
80	353.15	33.67	1	35	Total Pressure, P	0.114	1 Ethene in Liquid	0.9621	Ethene in Gas
80	353.15	38.70	1	40	Total Pressure, P	0.864	Acetone in Liquid, 1	0.0326	Acetone in Gas, 1
80	353.15	38.70	1	40	Total Pressure, P	0.136	1 Ethene in Liquid	0.9674	Ethene in Gas
80	353.15	43.66	1	45	Total Pressure, P	0.854	Acetone in Liquid, 1	0.0298	Acetone in Gas, 1
80	353.15	43.66	1	45	Total Pressure, P	0.146	1 Ethene in Liquid	0.9702	Ethene in Gas
80	353.15	48.65	1	50	Total Pressure, P	0.832	Acetone in Liquid, 1	0.0270	Acetone in Gas, 1
80	353.15	48.65	1	50	Total Pressure, P	0.168	1 Ethene in Liquid	0.9730	Ethene in Gas
80	353.15	53.67	1	55	Total Pressure, P	0.812	Acetone in Liquid, 1	0.0242	Acetone in Gas, 1
80	353.15	53.67	1	55	Total Pressure, P	0.188	1 Ethene in Liquid	0.9758	Ethene in Gas
80	353.15	58.63	1	60	Total Pressure, P	0.800	Acetone in Liquid, 1	0.0228	Acetone in Gas, 1
80	353.15	58.63	1	60	Total Pressure, P	0.200	1 Ethene in Liquid	0.9772	Ethene in Gas
80	353.15	63.62	1	65	Total Pressure, P	0.772	Acetone in Liquid, 1	0.0212	Acetone in Gas, 1
80	353.15	63.62	1	65	Total Pressure, P	0.228	1 Ethene in Liquid	0.9788	Ethene in Gas
80	353.15	68.62	1	70	Total Pressure, P	0.766	Acetone in Liquid, 1	0.0197	Acetone in Gas, 1
80	353.15	68.62	1	70	Total Pressure, P	0.234	1 Ethene in Liquid	0.9803	Ethene in Gas
80	353.15	73.61	1	75	Total Pressure, P	0.748	Acetone in Liquid, 1	0.0185	Acetone in Gas, 1
80	353.15	73.61	1	75	Total Pressure, P	0.252	1 Ethene in Liquid	0.9815	Ethene in Gas
100	373.15	1.86	1	5	Total Pressure, P	0.997	Acetone in Liquid, 1	0.6280	Acetone in Gas, 1
100	373.15	1.86	1	5	Total Pressure, P	0.003	1 Ethene in Liquid	0.3720	Ethene in Gas
100	373.15	7.37	1	10	Total Pressure, P	0.980	Acetone in Liquid, 1	0.2634	Acetone in Gas, 1
100	373.15	7.37	1	10	Total Pressure, P	0.020	1 Ethene in Liquid	0.7366	Ethene in Gas
100	373.15	12.49	1	15	Total Pressure, P	0.962	Acetone in Liquid, 1	0.1676	Acetone in Gas, 1
100	373.15	12.49	1	15	Total Pressure, P	0.038	1 Ethene in Liquid	0.8324	Ethene in Gas
100	373.15	17.53	1	20	Total Pressure, P	0.946	Acetone in Liquid, 1	0.1234	Acetone in Gas, 1
100	373.15	17.53	1	20	Total Pressure, P	0.054	1 Ethene in Liquid	0.8766	Ethene in Gas
100	373.15	22.28	1	25	Total Pressure, P	0.928	Acetone in Liquid, 1	0.1090	Acetone in Gas, 1
100	373.15	22.28	1	25	Total Pressure, P	0.072	1 Ethene in Liquid	0.8910	Ethene in Gas
100	373.15	27.53	1	30	Total Pressure, P	0.912	Acetone in Liquid, 1	0.0822	Acetone in Gas, 1
100	373.15	27.53	1	30	Total Pressure, P	0.088	1 Ethene in Liquid	0.9178	Ethene in Gas
100	373.15	32.52	1	35	Total Pressure, P	0.894	Acetone in Liquid, 1	0.0710	Acetone in Gas, 1
100	373.15	32.52	1	35	Total Pressure, P	0.106	1 Ethene in Liquid	0.9290	Ethene in Gas
100	373.15	37.52	1	40	Total Pressure, P	0.876	Acetone in Liquid, 1	0.0621	Acetone in Gas, 1
100	373.15	37.52	1	40	Total Pressure, P	0.124	1 Ethene in Liquid	0.9379	Ethene in Gas
100	373.15	42.51	1	45	Total Pressure, P	0.856	Acetone in Liquid, 1	0.0553	Acetone in Gas, 1
100	373.15	42.51	1	45	Total Pressure, P	0.144	1 Ethene in Liquid	0.9447	Ethene in Gas
100	373.15	47.50	1	50	Total Pressure, P	0.844	Acetone in Liquid, 1	0.0500	Acetone in Gas, 1
100	373.15	47.50	1	50	Total Pressure, P	0.156	1 Ethene in Liquid	0.9500	Ethene in Gas
100	373.15	52.48	1	55	Total Pressure, P	0.832	Acetone in Liquid, 1	0.0458	Acetone in Gas, 1
100	373.15	52.48	1	55	Total Pressure, P	0.168	1 Ethene in Liquid	0.9542	Ethene in Gas
100	373.15	57.46	1	60	Total Pressure, P	0.812	Acetone in Liquid, 11	0.0423	Acetone in Gas, 1
100	373.15	57.46	1	60	Total Pressure, P	0.188	1 Ethene in Liquid	0.9577	Ethene in Gas
100	373.15	62.45	1	65	Total Pressure, P	0.790	Acetone in Liquid, 1	0.0392	Acetone in Gas, 1
100	373.15	62.45	1	65	Total Pressure, P	0.210	1 Ethene in Liquid	0.9608	Ethene in Gas
100	373.15	67.44	1	70	Total Pressure, P	0.776	Acetone in Liquid, 1	0.0366	Acetone in Gas, 1
100	373.15	67.44	1	70	Total Pressure, P	0.224	1 Ethene in Liquid	0.9634	Ethene in Gas

Notes:
¹ Calculated by compiler.

Method/Apparatus/Procedure:
The equipment essentially consisted of an autoclave immersed in a constant temperature bath and connected to a membrane pressure gauge.

Henry's constants for the lower pressure region and the solubilities for a pressure of 1 atm as estimated by the compiler are:

   T/K      H, atm/mole fraction     x, mole fraction
   263.15             125                        0.00800
   283.15            225                      0.00444
   303.15            244                  0.00410
   323.15        286                       0.00351
   353.15        300                       0.00333
   373.15        313                       0.00319

Source and Purity of Materials:
   The sources and purities of gas and solvent were not specified.

Estimated Errors:
   Solubility: δx/mole fraction = ± 0.002 (Authors)
   Temperature: δT/K = ± 0.2
   Pressure: δp/atm = ± 0.05