IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Ethene with 2-Propanone (acetone)

Components:
   (1) 2-Propanone (acetone); C3H6O; [67-64-1]  NIST Chemistry WebBook for detail
   (2) Ethene; C2H4; [74-85-1]  NIST Chemistry WebBook for detail

Original Measurements:
   Shenderei, E.R.; Zel ' venskii, Ya.D.; Ivanovskii, F.P., Zhur. Fiz. Khim. 1962, 36, 801-808.

Variables:
   Temperature = 228.05 K to 248.15 K
   Pressure = 0.101 to 1.82 MPa

Prepared By:
   C.L. Young

Experimental Data:   (Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
  
T/KPressure [bar]Mole Fraction (x1)x1 NoteSolubilitySolubility Note
248.151.00.0255in liquid, x10.02+
248.153.00.0750in liquid, x30.98+
248.155.10.1300in liquid, x57.09+
248.1510.10.2825in liquid, x150.55+
248.1512.20.3500in liquid, x205.75+
248.1515.20.4680in liquid, x336.13+
248.1518.20.6100in liquid, x597.65+
238.151.00.0320in liquid, x12.61+
238.153.00.1000in liquid, x42.46+
238.155.10.1650in liquid, x75.51+
238.1510.10.3825in liquid, x236.88+
238.1512.20.5125in liquid, x402.11+
238.1515.20.8100in liquid, x1628.0+
228.051.00.0410in liquid, x16.35+
228.053.00.1275in liquid, x55.87+
228.055.00.2230in liquid, x109.66+
228.0510.10.6050in liquid, x515.50+
Notes:
   +  cm3g–1 at P = 101.325 kPa.

Method/Apparatus/Procedure:
   Glass equilibrium cell fitted with a magnetic stirrer. Pressure measured with a Bourdon gauge. Samples of liquid analyzed by stripping out ethene. Details in Ref. 1.

Source and Purity of Materials:
   1. Prepared from ethanol by dehydration and purified by absorption in cuprous chloride under pressure.
   2. Distilled.

Estimated Errors:
   Solubility: δxC2H4 = ± 2% (estimated by compiler)
   Temperature: δT/K = ± 0.1 (estimated by compiler)
   Pressure: δp/bar = ± 0.3 (estimated by compiler)

References:
   1. Shenderei, E.R.; Zelvenskii, Ya.D.; Ivanovskii, F.P., Khim. Prom. 1960, 370.