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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Ethene with 2-Propanone (acetone)
Components:
(1) 2-Propanone (acetone); C3H6O; [67-64-1]
NIST Chemistry WebBook
for detail
(2) Ethene; C2H4; [74-85-1]
NIST Chemistry WebBook
for detail
Original Measurements:
Shenderei, E.R.; Zel ' venskii, Ya.D.; Ivanovskii, F.P., Zhur. Fiz. Khim. 1962, 36, 801-808.
Variables:
Temperature = 228.05 K to 248.15 K
Pressure = 0.101 to 1.82 MPa
Prepared By:
C.L. Young
Experimental Data:
(Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
T/K
Pressure [bar]
Mole Fraction (x
1
)
x
1
Note
Solubility
Solubility Note
248.15
1.0
0.0255
in liquid, x
10.02
+
248.15
3.0
0.0750
in liquid, x
30.98
+
248.15
5.1
0.1300
in liquid, x
57.09
+
248.15
10.1
0.2825
in liquid, x
150.55
+
248.15
12.2
0.3500
in liquid, x
205.75
+
248.15
15.2
0.4680
in liquid, x
336.13
+
248.15
18.2
0.6100
in liquid, x
597.65
+
238.15
1.0
0.0320
in liquid, x
12.61
+
238.15
3.0
0.1000
in liquid, x
42.46
+
238.15
5.1
0.1650
in liquid, x
75.51
+
238.15
10.1
0.3825
in liquid, x
236.88
+
238.15
12.2
0.5125
in liquid, x
402.11
+
238.15
15.2
0.8100
in liquid, x
1628.0
+
228.05
1.0
0.0410
in liquid, x
16.35
+
228.05
3.0
0.1275
in liquid, x
55.87
+
228.05
5.0
0.2230
in liquid, x
109.66
+
228.05
10.1
0.6050
in liquid, x
515.50
+
Notes:
+
cm
3
g
1
at
P
= 101.325 kPa.
Method/Apparatus/Procedure:
Glass equilibrium cell fitted with a magnetic stirrer. Pressure measured with a Bourdon gauge. Samples of liquid analyzed by stripping out ethene. Details in Ref. 1.
Source and Purity of Materials:
1. Prepared from ethanol by dehydration and purified by absorption in cuprous chloride under pressure.
2. Distilled.
Estimated Errors:
Solubility: δ
x
C
2
H
4
= ± 2% (estimated by compiler)
Temperature: δ
T
/K = ± 0.1 (estimated by compiler)
Pressure: δ
p
/bar = ± 0.3 (estimated by compiler)
References:
1. Shenderei, E.R.; Zelvenskii, Ya.D.; Ivanovskii, F.P., Khim. Prom. 1960, 370.