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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Naphthalene with Dichloromethane
Components:
(1) Dichloromethane; CH2Cl2; [75-09-2]
NIST Chemistry WebBook
for detail
(2) Naphthalene; C10H8; [91-20-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Chang, W., Ph.D Dissertation, North Dakota State University, North Dakota, USA (1969).
Variables:
Temperature = 298 K
Prepared By:
W.E. Acree, Jr.
Experimental Data:
(Notes on the Nomenclature)
t/°C
Mole Fraction x
1
Mole Fraction x
2
25.0
0.330
0.670
Method/Apparatus/Procedure:
Constant temperature bath and a precision thermometer.
Mixtures of known concentrations sealed in glass ampoules and placed in constant temperature to equilibrate. Samples were rotated while bath temperature slowly increased. Solubility determined by visual noting the temperature at which the last trace of solid solute disappeared. Solubilities at 298 K interpolated from experimental values using ln x
1
versus 1/T graph.
Source and Purity of Materials:
(1) Purity, source and purification procedures not specified.
(2) Reagent Grade, J.T. Baker Chemical Company, USA, was used as received.
Estimated Errors:
Temperature: T/K: ± 0.1. x
1
: precision ± 2 % (relative error; compiler).