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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Fluorene with 1,4-Dimethylbenzene
Components:
(1) 1,4-Dimethylbenzene; C8H10; [106-42-3]
NIST Chemistry WebBook
for detail
(2) Fluorene; C13H10; [86-73-7]
NIST Chemistry WebBook
for detail
Original Measurements:
Mortimer, F.S., J. Am. Chem. Soc. 1923, 45, 633-641.
Variables:
Temperature = Temperature
Prepared By:
W.E. Acree, Jr.
Experimental Data:
(Notes on the Nomenclature)
T/K
Mole Fraction x
1
Mole Fraction x
2
273
0.055
0.945
293
0.112
0.888
313
0.193
0.807
333
0.327
0.673
353
0.513
0.487
Method/Apparatus/Procedure:
Experimental procedure not given in the reference. Compiler speculates that the experimental values were, in all likelihood, determined by a gravimetric method, which was common practice during this era. The method probably involved equilibrating excess solute and solvent in sealed containers, transfer of weighed aliquots of saturated solution to tared containers, evaporation of solvent, and weighing of solid residue that remained.
Source and Purity of Materials:
(1) Purity and chemical source not given. Paper states only that the solute was carefully purified.
(2) Purity and chemical source not given. Paper states only that the solute was carefully purified.
Estimated Errors:
Temperature: T/K: ± 2 (by compiler). x
1
: ± 8 % (relative error, by compiler).