IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Fluorene with 1,4-Dimethylbenzene

Components:
   (1) 1,4-Dimethylbenzene; C8H10; [106-42-3]  NIST Chemistry WebBook for detail
   (2) Fluorene; C13H10; [86-73-7]  NIST Chemistry WebBook for detail

Original Measurements:
   Mortimer, F.S., J. Am. Chem. Soc. 1923, 45, 633-641.

Variables:
   Temperature = Temperature

Prepared By:
   W.E. Acree, Jr.

Experimental Data:   (Notes on the Nomenclature)
  
T/KMole Fraction x1Mole Fraction x2
2730.0550.945
2930.1120.888
3130.1930.807
3330.3270.673
3530.5130.487
Method/Apparatus/Procedure:
   Experimental procedure not given in the reference. Compiler speculates that the experimental values were, in all likelihood, determined by a gravimetric method, which was common practice during this era. The method probably involved equilibrating excess solute and solvent in sealed containers, transfer of weighed aliquots of saturated solution to tared containers, evaporation of solvent, and weighing of solid residue  that remained.

Source and Purity of Materials:
   (1) Purity and chemical source not given. Paper states only that the solute was carefully purified.
   (2) Purity and chemical source not given. Paper states only that the solute was carefully purified.

Estimated Errors:

   Temperature: T/K: ± 2 (by compiler). x1: ± 8 % (relative error, by compiler).