IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Naphthalene with n-Hexane

Components:
   (1) n-Hexane; C6H14; [110-54-3]  NIST Chemistry WebBook for detail
   (2) Naphthalene; C10H8; [91-20-3]  NIST Chemistry WebBook for detail

Original Measurements:
   Heric, E.L.; Posey, C.D., J. Chem. Eng. Data 1964, 9, 35-43.

Variables:
   Temperature = 298 K

Prepared By:
   W.E. Acree, Jr.

Experimental Data:   (Notes on the Nomenclature)
  
t/°CMole Fraction x1Mole Fraction x2
25.00.11680.8832
Method/Apparatus/Procedure:
   Constant temperature bath, thermometer, and a precision refractometer.
Excess solute and solvent placed in glass bottles and allowed to equilibrate with gentle agitation for several days at constant temperature. Refractive indices of saturated solutions were measured and solubilities obtained using a calibration verified by making repetitive measurements after several additional  days.

Source and Purity of Materials:
   (1) Eastman Chemical Company, Rochester, New York, USA, was used as received.
   (2) Spectroquality, Matheson, Coleman and Bell, USA, was dried over phosphorous pentoxide and distilled to a final purity of 99.99 %.

Estimated Errors:

   Temperature: T/K: precision ± 0.01. x1: precision ± 0.0005.