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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Naphthalene with n-Hexane
Components:
(1) n-Hexane; C6H14; [110-54-3]
NIST Chemistry WebBook
for detail
(2) Naphthalene; C10H8; [91-20-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Heric, E.L.; Posey, C.D., J. Chem. Eng. Data 1964, 9, 35-43.
Variables:
Temperature = 298 K
Prepared By:
W.E. Acree, Jr.
Experimental Data:
(Notes on the Nomenclature)
t/°C
Mole Fraction x
1
Mole Fraction x
2
25.0
0.1168
0.8832
Method/Apparatus/Procedure:
Constant temperature bath, thermometer, and a precision refractometer.
Excess solute and solvent placed in glass bottles and allowed to equilibrate with gentle agitation for several days at constant temperature. Refractive indices of saturated solutions were measured and solubilities obtained using a calibration verified by making repetitive measurements after several additional days.
Source and Purity of Materials:
(1) Eastman Chemical Company, Rochester, New York, USA, was used as received.
(2) Spectroquality, Matheson, Coleman and Bell, USA, was dried over phosphorous pentoxide and distilled to a final purity of 99.99 %.
Estimated Errors:
Temperature: T/K: precision ± 0.01. x
1
: precision ± 0.0005.