IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Trichloromethane (chloroform) with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Trichloromethane (chloroform); CHCl3; [67-66-3]  NIST Chemistry WebBook for detail

Original Measurements:
   Moore, B.; Roaf, H.E., Proc. Roy. Soc., London 1904, 73, 382-412.

Variables:
   Temperature = 286 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C102 * Mass Fraction w1103 * Mole Fraction x1 (compiler)102 * w1/M1 (compiler) [mol g**-1]
130.951.4457.96 x 10-3
Method/Apparatus/Procedure:
   Pure trichloromethane was dropped from a fine capillary pipette into a tared graduated flask containing distilled water. Samples in a series of flasks of various sizes were prepared and placed on a rotary shaking machine. After several days shaking, an  equilibrium was established. The solubility was determined from the decreased amount of trichloromethane.

Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled.

Estimated Errors:
   Solubility: ± 5 %.
   Temperature: ± 1 K (compiler).