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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Trichloromethane (chloroform) with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Trichloromethane (chloroform); CHCl3; [67-66-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Moore, B.; Roaf, H.E., Proc. Roy. Soc., London 1904, 73, 382-412.
Variables:
Temperature = 286 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* Mass Fraction w
1
10
3
* Mole Fraction x
1
(compiler)
10
2
* w
1
/M
1
(compiler) [mol g**-1]
13
0.95
1.445
7.96 x 10
-3
Method/Apparatus/Procedure:
Pure trichloromethane was dropped from a fine capillary pipette into a tared graduated flask containing distilled water. Samples in a series of flasks of various sizes were prepared and placed on a rotary shaking machine. After several days shaking, an equilibrium was established. The solubility was determined from the decreased amount of trichloromethane.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Distilled.
Estimated Errors:
Solubility: ± 5 %.
Temperature: ± 1 K (compiler).