IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 1-Bromoheptane with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1-Bromoheptane; C7H15Br; [629-04-9]  NIST Chemistry WebBook for detail

Original Measurements:
   Miller, M.M.; Wasik, S.P.; Huang, G.L.; Shiu, W.Y.; Mackay, D., Environ. Sci. Technol. 1985, 19, 522-529.

Variables:
   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C102 * Mass Fraction w1 (compiler) 107 * Mole Fraction x1 (compiler)n1/V2 [mol m**-3]
256.68 x 10-46.723.71 x 10-2
Method/Apparatus/Procedure:
   A saturated aqueous solution was prepared by passing of water through a column which was packed with glass beads coated with 1-bromoheptane. The saturated solution was then pumped through an extractor column and  1-bromoheptane was extracted directly into an analytical column. The samples were analyzed with a liquid chromatograph equipped with both an UV ab-sorbance and a fluorescence detector with excitation filters.  The peak area was established using a Hewlett-Packard recorder.

Source and Purity of Materials:
   (1) Eastman Kodak Company. Commercial quality, used as received.
   (2) Double distilled.

Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 1.0 K (compiler).