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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
2-Methyl-1-propanol with Mestiylene (1,3,5-trimethylbenzene) and Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 2-Methyl-1-propanol (isobutyl alcohol); C4H10O; [78-83-1]
NIST Chemistry WebBook
for detail
(3) Mesitylene (1,3,5-trimethylbenzene); C9H12; [108-67-8]
NIST Chemistry WebBook
for detail
Original Measurements:
Letcher, T.M.; Siswana, P.M., Fluid Phase Equilib. 74, 203 (1992).
Variables:
Temperature = 298 K
Prepared By:
A. Skrzecz
Experimental Data:
(Notes on the Nomenclature)
Compositions along the saturation curve
t/°C
T/K
Mass Fraction w
1
(compiler)
Mass Fraction w
2
(compiler)
Mole Fraction x
1
Mole Fraction x
2
25.0
298.2
0.000
0.000
0.000
0.000
25.0
298.2
0.081
0.000
0.021
0.000
25.0
298.2
0.832
0.000
0.546
0.000
25.0
298.2
0.805
0.049
0.560
0.021
25.0
298.2
0.719
0.180
0.577
0.089
25.0
298.2
0.646
0.276
0.568
0.150
25.0
298.2
0.566
0.378
0.549
0.226
25.0
298.2
0.479
0.479
0.504
0.311
25.0
298.2
0.387
0.583
0.445
0.413
25.0
298.2
0.294
0.687
0.368
0.531
25.0
298.2
0.198
0.792
0.271
0.670
25.0
298.2
0.100
0.896
0.149
0.825
25.0
298.2
0.050
0.948
0.077
0.906
25.0
298.2
0.000
0.9998
0.000
0.999
Compositions of coexisting phases
t/°C
T/K
Mass Fraction w
1
(compiler)
Mass Fraction w
2
(compiler)
Mole Fraction x
1
Mole Fraction x
2
Comment(s)
25.0
298.2
0.000
0.9998
0.000
0.999
organic-rich phase
25.0
298.2
0.143
0.850
0.205
0.752
organic-rich phase
25.0
298.2
0.310
0.669
0.382
0.509
organic-rich phase
25.0
298.2
0.477
0.480
0.503
0.312
organic-rich phase
25.0
298.2
0.832
0.000
0.546
0.000
organic-rich phase
25.0
298.2
0.000
0.000
0.000
0.000
water-rich phase
25.0
298.2
0.028
0.000
0.007
0.000
water-rich phase
25.0
298.2
0.044
0.000
0.011
0.000
water-rich phase
25.0
298.2
0.063
0.000
0.016
0.000
water-rich phase
25.0
298.2
0.081
0.000
0.021
0.000
water-rich phase
Method/Apparatus/Procedure:
The points on the binodal curve were determined by the formation of a cloudy mixture on shaking after the addition of a known mass of one component to a mixture of known masses of the other two components. Precision weighing syringes were used as described in Ref. 1. Tie line compositions were determined by the refractive index method reported in Ref. 2 and complementary method using the Karl Fischer titrations as reported in Ref. 3.
Source and Purity of Materials:
(1) Merck, AR grade; distilled, dried by the addition of anhydrous potassium carbonate, distilled; purity better than 99.6 mole % by glc.
(2) BDH; used as received; purity better than 99.6 mole % by glc.
(3) Source not specified.
Estimated Errors:
Solubility: Not reported.
Temperature: Estimated comp. 0.005 mole fraction on the binodal curve and 0.01 mole fraction for tie lines (estimated by the authors).
References:
1
T. M. Letcher, S. Wootten, B. Shuttleworth, and C. Heward, J. Chem. Thermodyn. 18, 1037 (1986).
2
S. W. Briggs and E. W. Comings, Ind. Eng. Chem. 35, 411 (1943).
3
T. M. Letcher, P. M. Siswana, P. Van der Watt, and S. Radloff, J. Chem. Thermodyn. 21, 1053 (1989).