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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Acetonitrile with Nonanoic acid
Components:
(1) Acetonitrile; C2H3N; [75-05-8]
NIST Chemistry WebBook
for detail
(2) Nonanoic acid; C9H18O2; [112-05-0]
NIST Chemistry WebBook
for detail
Original Measurements:
Hoerr, C.W.; Ralston, A.W., J. Org. Chem. 9, 329-37 (1944).
Variables:
Temperature = 273 K to 283 K
Prepared By:
Valerii P. Sazonov
Experimental Remarks:
The solubilities of nonanoic acid (2) in acetonitrile (1) in mass percent over the indicated temperature range were reported in graphical form and in a table.
Experimental Data:
(Notes on the Nomenclature)
Solubility of nonanoic acid (2) in acetonitrile (1)
t/°C
T/K
g
2
/100 g solution
10
2
* Mass Fraction w
2
(compiler)
Mole Fraction x
2
(compiler)
0.0
273.2
51
33.8
0.117
0.8*
274.0
-
38.8
0.141
2.5*
275.7
-
56.3
0.251
3.1*
276.3
-
72.0
0.400
5.8*
279.0
-
88.0
0.656
10.0
283.2
3470
97.2
0.900
Notes:
*
The compiler extracted these data from the published graphs.
Method/Apparatus/Procedure:
The synthetic method, as described elsewhere,
1
was used. No details were reported.
Source and Purity of Materials:
(1) Source not specified; purity not specified; dried and twice distilled.
(2) Source not specified; purified according to Pool and Ralston
2
; freezing point = 12.25 °C.
Estimated Errors:
Solubility: Not reported.
Temperature: Not reported.
References:
1. C. W. Hoerr, E. F. Binkerd, W. O. Pool, and A. W. Ralston, J. Org. Chem. 9, 68 (1944).
2. W. O. Pool and A. W. Ralston, Ind. Eng. Chem. 34, 1104 (1942).