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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Acetonitrile with Decanoic acid
Components:
(1) Decanoic acid; C10H20O2; [334-48-5]
NIST Chemistry WebBook
for detail
(2) Acetonitrile; C2H3N; [75-05-8]
NIST Chemistry WebBook
for detail
Original Measurements:
Hoerr, C.W.; Ralston, A.W., J. Org. Chem. 9, 329-37 (1944).
Variables:
Temperature = 273 K to 303 K
Prepared By:
Valerii P. Sazonov
Experimental Remarks:
The solubilities of decanoic acid (2) in acetonitrile (1) in mass percent over the indicated temperature range were reported in graphical form and in a table.
Experimental Data:
(Notes on the Nomenclature)
Solubility of decanoic acid (2) in acetonitrile (1)
t/°C
T/K
g
2
/100 g solution
10
2
* Mass Fraction w
2
(compiler)
Mole Fraction x
2
(compiler)
0.0
273.2
11.8
10.6
0.0275
3.0*
276.2
-
12.1
0.0318
8.2*
281.4
-
15.4
0.0416
10.0
283.2
21.0
17.4
0.0478
13.7*
286.9
-
21.4
0.0609
19.7*
292.9
-
36.5
0.121
20.0
293.2
66.0
39.8
0.136
20.9*
294.1
-
44.5
0.160
22.3*
295.5
-
63.0
0.289
24.2*
297.4
-
81.8
0.517
27.5*
300.7
-
92.5
0.746
30.0
303.2
7600
98.7
0.948
Notes:
*
These data were extracted by the compiler from the published graphs.
Method/Apparatus/Procedure:
The synthetic method, as described elsewhere,
1
was used. No details were reported.
Source and Purity of Materials:
(1) Source not specified; purity not specified; dried and twice distilled.
(2) Purified according to Pool and Ralston
2
; freezing point = 31.24 °C.
Estimated Errors:
Solubility: Not specified.
Temperature: Not specified.
References:
1. C. W. Hoerr, E. F. Binkerd, W. O. Pool, and A. W. Ralston, J. Org. Chem. 9, 68 (1944).
2. W. O. Pool and A. W. Ralston, Ind. Eng. Chem. 34, 1104 (1942).