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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Acetonitrile with Potassium iodide
Components:
(1) Acetonitrile; C2H3N; [75-05-8]
NIST Chemistry WebBook
for detail
(2) Potassium iodide; KI; [7681-11-0]
NIST Chemistry WebBook
for detail
Original Measurements:
Il'in, K.K., Varlamova, T.M., and Lelyukhin, S.V., Phase Equilibriums and Thermal Analysis (in Russian), Perm', 124 (1988).
Variables:
Temperature = 283 K to 333 K
Prepared By:
Valerii P. Sazonov
Experimental Data:
(Notes on the Nomenclature)
Solubility of potassium iodide (2) in acetonitrile (1)
t/°C
T/K
10
2
* Mass Fraction w
2
Mole Fraction x
2
(compiler)
10.0
283.2
2.25
0.0057
20.0
293.2
2.07
0.0052
25.0
298.2
1.98
0.0050
30.0
303.2
1.96
0.0049
40.0
313.2
1.84
0.0046
50.0
323.2
1.71
0.0043
60.0
333.2
1.60
0.0040
Method/Apparatus/Procedure:
The analytical method was used. (1) and (2) were placed in a vessel without contact to atmospheric moisture. With continuous stirring equilibrium was established in 6-7 hours. Salt content in saturated solutions determined by gravimetrically.
Source and Purity of Materials:
(1) Source not specified; pure grade reagent; dried and purified.
(2) Source not specified; very pure reagent; dried in vacuum.
Estimated Errors:
Solubility: relative error ± 0.1 %.
Temperature: ± 0.1 K.