INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY
ANALYTICAL CHEMISTRY DIVISION
COMMISSION ON SOLUBILITY DATA
 
SOLUBILITY DATA SERIES
 
Editor-in-Chief
A. S. KERTES
 
Volume 26
SULFITES, SELENITES AND TELLURITES
 
Volume Editors
MARY R. MASSON University of Aberdeen Scotland, UK
 
Co-Editors
H. D. LUTZ University of Siegen Federal Republic of Germany
B. ENGELEN University of Siegen Federal Republic of Germany
 
Contributors
M. R. MASSON
H. D. LUTZ
B. ENGELEN
 
Copyright 1986 International Union of Pure and Applied Chemistry



Contents v
Foreword viii
Preface xi
Introduction to the Solubility of Solids in Liquids xvi
 
1 Sodium Bisulfite
  1.1 Evaluation 1
  1.2 Binary system 8
  1.3 Ternary systems 16
  1.4 More complex systems 59
 
2 SodIum pyrosulfIte (sodIum dIsulflte)
  2.1 Evaluation 72
  2.2 Binary system 72
  2.3 Ternary systems 76
  2.4 More complex systems 78
 
3 Potassium sulfite
  3.1 Evaluation 90
  3.2 Binary system 93
  3.3 Ternary systems 95
  3.4 More complex systems 107
 
4 Potassium pyrosulfite (potassium disulfite)
  4.1 Evaluation 108
  4.2 Binary system 110
 
5 Ammonium sulfite
  5.1 Evaluation 113
  5.2 Binary system 117
  5.3 Ternary systems 121
  5.4 More complex systems 141
 
6 Ammonium pyrosulfite (ammonium disulfite)
  6.1 Evaluation 144
  6.2 Binary system 146
  6.3 Ternary systems 147
 
7 Beryllium sulfite 152
 
8 Magnesium sulfite
  8.1 Evaluation 153
  8.2 Binary system 160
  8.3 Ternary systems 165
  8.4 More complex systems 180
 
9 Calcium sulfite
  9.1 Evaluation 187
  9.2 Binary system 194
  9.3 Ternary systems 196
  9.4 More complex systems 220
 
10 Strontium sulfite 236
 
11 Barium sulfite 240
 
12 Manganese (II) sulfite 248
 
13 Iron(II) sulfite 252
 
14 Cobalt (II) sulfite 256
 
15 Nickel (II) sulfite 258
 
16. Copper (I) sulfite 260
 
17 Copper (I,II) sulfite 262
 
18 Silver sulflte 267
 
19 Zinc sulfite 271
 
20 Cadmium sulfite 286
 
21 Mercury (I) sulfite 291
 
22. Lead (II) sulfite 293
 
23 Sodium selenite 303
 
24 Potassium selenite 322
 
25 Alkali-metal selenites
  25.1 Evaluation 331
  25.2 Lithium selenite 332
  25.3 Sodium pyroselenite (sodium diselenite) 333
  25.4 Sodium trihydrogen diselenite 336
  25.5 Potassium pyroselenite (diselenite) 338
  25.6 Potassium trihydrogen diselenite 340
  25.7 Ammonium selenite 342
  25.8 Ammonium pyroselenite (diselenite) 344
  25.9 Ammonium trihydrogen diselenite 346
 
26 Sparingly soluble selenites
  26.1 Evaluation 348
  26.2 Beryllium selenite 353
  26.3 Magnesium selenite 354
  26.4 Calcium selenite 356
  26.5 Strontium selenite 358
  26.6 Barium selenite 362
  26.7 Manganese (II) selenite 367
  26.8 Iron(III) selenite 368
  26.9 Cobalt (II) selenite 370
  26.10 Nickel (II) selenite 374
  26.11 Copper (II) selenite 377
  26.12 Silver selenite 380
  26.13 Zinc selenite 389
  26.14 Cadmium selenite 391
  26.15 Mercury( I) selenite 394
  26.16 Mercury (II) selenite 397
  26.17 Lead( II) selenite 401
 
27 Tellurites (salts of the tellurate (IV) ion)
  27.1 Evaluation 403
  27.2 Lithium tellurite 406
  27.3 Sodium tellurite 407
  27.4 Cesium tellurite 419
  27.5 Barium tellurite 420
  27.6 Cobalt (II) tellurite 421
  27.7 Nickel (II) tellurite 422
  27.8 Copper (II) tellurite 423
  27.9 Silver tellurite 424
  27.1 Lead( II) tellurite 427
 
System Index 429
Registry Number Index 443
Author Index 446