INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY
ANALYTICAL CHEMISTRY DIVISION
COMMISSION ON SOLUBILITY DATA
 
SOLUBILITY DATA SERIES
 
Editor-in-Chief
A. S. KERTES


Volume 21
AMMONIA, AMINES, PHOSPHINE, ARSINE,
STIBINE, SILANE, GERMANE AND STANNANE IN ORGANIC SOLVENTS
 
Volume Editors
COLIN L. YOUNG University of Melbourne Parkville, Victoria, Australia
PETER G. T. FOGG Polytechnic of North London Holloway, London, UK
 
Contributors
H. LAWRENCE CLEVER Emory University Atlanta, Georgia, USA
WALTER HAYDUK University of Ottawa Ottawa, Ontario, Canada
 
Copyright © 1985 International Union of Pure and Applied Chemistry


Contents v
Foreword vii
Preface x
The solubility of Gases in Liquids xi
 
1. Ammonia Solubilities 1
  1.1     Critical evaluation of data 1
  1.2     Hydrocarbons 13
  1.3     Alcohols 35
  1.4     Other organic compounds containing oxygen 55
  1.5 Organic compounds containing halogen 67
  1.6 Organic compounds containing nitrogen 71
  1.7 Miscellaneous compounds 79
2. Critical Evaluation of Data on Amine Solubilities 80
 
3. Methanamine Solubilities 92
  3.1 Hydrocarbons 92
  3.2     Alcohols 101
  3.3     Other organic compounds containing oxygen 110
  3.4     Organic compounds containing nitrogen 113
  3.5 Organic compounds containing halogen 128
4. N-Methylmethanamine Solubilities 135
  4.1 Hydrocarbons 135
  4.2 Alcohols 142
  4.3 Other organic compounds containing oxygen 154
  4.4 Organic compounds containing nitrogen 159
  4.5 Organic compounds containing halogen 171
5. N,N-Dimethylmethanamine 178
  5.1 Hydrocarbons 178
  5.2 Alcohols 186
  5.3 Other organic compounds containing oxygen 198
  5.4 Organic compounds containing nitrogen 207
  5.5 Organic compounds containing halogen 223
6. Solubilities of Deuterated Amines 234
 
7. Solubilities of Other Amines 252
 
8. Phosphine Solubilities 281
 
9. Arsine Solubilities 302
 
10. Stibine Solubilities 310
 
11. Solubilities of Silane, Germane and Stannane 315
 
System Index 329
Registry Number Index 339
Author Index 343


Chemical Substances
1,1,1-Trichloro-2-hydroxyethane; 1,1-Bicyclohexyl; 1,1'-Oxybisoctane; 1,2,3 propanetriol; 1,2,3-propanetrial triacetate; 1,2,3-Propanetriol; 1,2,3-propanetriol triacetate; 1,2-Benzenedicarboxylic acid; 1,2-Benzenedicarboxylic acid, dibutyl ester; 1,2-Benzenedicarboxylic acid, didecyl ester; 1,2-ethanediamine, N,N'-bis(2-aminoethyl)­; 1,2-Ethanediamine, N,N-bis-(2-aminoethyl)­; 1,2-Ethanediol; 1,3,5-Trimethylbenzene; 1,3-Butanediol; 1,3-Butylene glycol; 1,4-Dioxane; 1,6-Hexanediamine; 1-Bromonaphthalene; 1-butanamine; 1-Butanol; 1-Butanol, 3-methyl­; 1-butanol, 3-methyl-; 1-Methyl-2-nitrobenzene; 1-Methylnaphthalene; 1-nonanamine, n-nonyl­; 1-Nonanamine, n-nonyl-; 1-Octanamine; 1-Octanol; 1-Phenyl benzoate; 1-phenyl ester; 1-propanamine; 1-propanamine-d; 1-Propanol; 1-Propanol, 2-methyl­; 1-propanol,2-methyl­; 2,2'-(1,2-ethanediylbis(oxy))bisethanol; 2,2,4-trimethylpentane; 2-Aminoethanol; 2-butanamine; 2-Butanol; 2-Butanone; 2-Furancarboxdldehyde; 2-Heptane, 2,6-dimethyl-; 2-methyl-1-propanamine; 2-Methyl-1-propanol; 2-Pinene; 2-propanamine; 2-propanamine-d; 2-Propanol; 2-Propanol, 2-methyl­; 2-propanone; 2-Pyrrolidinone, 1-methyl-; 3-Methyl-1-butanol; 3-Oxo-butanoic acid; 3-oxo-ethyl ester; 3-Pentanone; Acetic acid; Acetic acid, ethyl ester; Acetic acid, octyl ester; Acetic, trifluoro-, acid; Acetone; Acetonitrile; Adiponitrile; ammonia; Aniline; arsine; benzenamine; benzenamine, N,N-diethyl­; benzenamine, N,N-dimethyl­; Benzenamine, N,N-dimethyl-; benzenamine, N-ethyl­; Benzenamine, N-ethyl-; benzenamine, N-methyl­; Benzenamine, N-methyl-; Benzene; Benzene alcohol; benzene chloro-; Benzene, (1-methylethyl)­; benzene, (chloromethyl)-; benzene, 1,3,5-trimethyl-; benzene, 1,3,5-trimethyl Methanamine,; Benzene, 1,3-5-trimethyl­; Benzene, 1,3-dimethyl-; benzene, 1-bromo-3-ethyl; Benzene, 1-bromo-3-methy1-; benzene, 1-bromo-3-methyl­; benzene, 1-methy1-2-nitro­; Benzene, 1-methy1-2-nitro-; Benzene, bromo­; Benzene, chloro­; Benzene, chloromethyl­; Benzene, dimethyl-; Benzene, ethoxy-; Benzene, hexafluoro-; Benzene, iodo; Benzene, methyl­; benzene, methyl-; Benzene, nitro­; Benzeneethanamine; Benzenemethanamine; Benzenemethanol; benzoic acid,; Benzoic acid, ethyl ester; Benzonitrile; Benzyl chloride; Benzylamine; Bicyclo(3,1,l)-hept-2-ene,2,6,6-trimethy1-; bicyclo(3,1,l)-hept-2-ene,2,6,6-trimethyl­; Bromo-3-methylbenzene; Bromobenzene; Bromotoluene; Butane; Butanenitrile; butanoic acid,; Butanoic acid, 3-oxo-, ethyl ester; Butyronitrile; carbon disulfide; carbon tetrachloride; Chlorobenzene; Chloroform; Cyclohexane; Cyclohexane, methyl-; Cyclohexane, undecafluoro(trifluoromethyl)-; cyclohexane,methyl-; Cyclohexanol; Cyclohexanone; cyclohexene; Cyclopentanone; Decahydronaphthalene; Decalin; Decane; Dichloroethylene; Diesel; Diethyl ether; Diethylene glycol; Dinonylamine; Dioctylether; Dipentylether; Dodecane; ethanamine; Ethanamine, N,N-diethyl­; ethanamine-d2; Ethane, (2-chloro-1,1-oxybis; ethane, 1,1'-oxybis­; ethane, 1,1'-oxybis-; Ethane, 1,2-dichloro­; ethane, 1,2-dichloro-; Ethanol; Ethanol, 2,2' -(1,2-ethanediylbis(oxy))bis­; Ethanol, 2,2'-(1,2-ethanediylbis(oxy))bis­; Ethanol, 2,2-(1,2-ethanediylbis(oxy))bis­; Ethanol, 2,2'-(oxybis(2,1-ethanediyloxy))bis; Ethanol, 2,2',2'nitrilotris­; Ethanol, 2,2,2-trichloro; Ethanol, 2,2,2-trichloro­; Ethanol, 2,2-dichloro-; Ethanol, 2,2'-oxybis­; ethanol, 2,2-oxybis­; Ethanol, 2-amino-; Ethanol, 2-chloro-; Ethanol, 2-ethoxy­; Ethanone, 1-phenyl; Ethene, 1,2-dichloro-; Ethene, tetrachloro-; Ethene, trichloro-; ethyl ester; Ethyl ether; Ethyl phenylether; Ethylbenzoate; Ethylene glycol; ethylester; formamide, N,N-dimethyl-; Forrnamide, N,N-dimethyl­; Furan,tetrahydro­; germane; Glycerol; Glyceryltriacetate; Heptane; Hexadecane; Hexamethylenedianine; Hexane; Hexanedinitrile; Hydrazine; Hydrazine, 1,1-dimethyl­; Hydrazine, methyl-; Hydrocyanic acid; iso-Butylamine; iso-Octane; Kerosine; Liquid paraffin; Mesitylene; methanamine; methanamine-d, N-methyl-; methanamine-d2; methanamine-d5; methan-d3-amine; Methane, dichloro-; methane, nitro­; Methane, nitro-; Methane, tetrachloro­; Methane, trichloro­; methane, trichloro-; Methanol; Methylcyclohexane; Methylphenylketone; Monoethanolamine; m-Xylene; N-(methyl-d3)-methan-d3-amine; N,N-Diethylaniline; N,N-Diethylbenzenamine; N,N-diethylethanamine; N,N-diethyl-ethanamine; N,N-dimethyl-; N,N-Dimethylaniline; N,N-Dimethylbenzenamine; N,N-Dimethylformamide; N,N-dimethylmethanamine; N,N-dimethylmethanimine; N,N-d-methylmethanamine; Naphthalene; Naphthalene, 1,2,3,4-tetrahydro­; naphthalene, 1-bromo­; Naphthalene, 1-bromo-; Naphthalene, 1-chloro; Naphthalene, 1-methyl-; naphthalene, cis-decahydro­; Naphthalene, cis-decahydro-; Naphthalene, decahydro; naphthalene, decahydro-; naphthalene, l-methyl­; naphthalene, tetrahydro­; Naphthalene, trans-decahydro­; N-Ethylaniline; N-Ethylbenzenamine; N-ethyl-ethanamine; Nitrobenzene; Nitromethane; Nitropropane; N-methyl ethanamine; N-Methylaniline; N-Methylbenzenamine; N-methylmethanamine; Nonane; N-Propylamine; Octane; Octane, 1,1'-oxybis­; octane, 1,1'-oxybis-; Octane, 1-chloro­; Octylamine; o-Nitrotoluene; Pentane; Pentane, 1,1'-oxybis­; pentane, 1,1-oxybis-; Pentane, 2,2,4-trimethyl-; Petroleum ether; phosphine; Phosphoric acid tributyl ester; Phosphorous acid, dibuthylester; Phosphorous acid, triethyl ester; Phosphorous acid, triphenyl ester; Phosphorus(ternary); propane,nitro-; propanenitrile; Propene,1,2-epoxy­; Propionitrile; Pyridine; Quinoline; silane; silane, tetramethyl­; Silane,tetramethyl­; Silane,triethoxy­; Silicic acid, tetraethyl ester; Silicone 702-DF; Silicone PFMS-4F; Silicone VKZH-94B; stannane; stibine; Tetrachloromethane; Tetralin; Tetramethylsilane; Toluene; Toluene,m-bromo-; Triacetin; Trichloromethane; Triethylamine; Triethylene glycol; Triethylenetetramine;


CAS Registry Numbers
100-44-7; 100-46-9; 100-47-0; 100-47-4; 100-51-6; 100-61-8; 101-02-0; 102-71-6; 102-76-1; 103-69-5; 103-73-1; 106-97-8; 107-06-2; 107-10-8; 107-12-0; 107-21-1; 107-88-0; 108-38-3; 108-67-8; 108-86-1; 108-87-2; 108-88-3; 108-90-7; 108-93-0; 108-94-1; 109-66-0; 109-74-0; 109-89-7; 109-99-9; 110-54-3; 110-80-5; 110-82-7; 110-83-8; 110-86-1; 111-44-4; 111-46-6; 111-65-9; 111-69-3; 111-84-2; 111-85-3; 111-86-4; 111-87-5; 112-14-1; 112-24-3; 112-27-6; 112-40-3; 112-60-7; 115-20-8; 119-64-2; 120-92-3; 121-44-8; 121-69-7; 122-52-1; 1222-52-1; 123-51-3; 123-91-1; 124-09-4; 124-18-5; 124-40-3; 126-73-8; 127-18-4; 1321-94-4; 1330-20-7; 13952-84-6; 141-43-5; 141-78-6; 141-97-9; 142-82-5; 14802-36-9; 2044-21-5; 22024-52-3; 2406-52-2; 25837-80-3; 2614-35-9; 29063-28-3; 302-01-2; 355-02-2; 3767-37-1; 392-56-3; 493-01-6; 493-02-7; 540-59-0; 540-84-1; 544-76-3; 5581-55-5; 5587-98-2; 56-23-5; 56-81-5; 57-14-7; 5852-45-9; 591-50-4; 598-38-9; 59826-67-4; 60-29-7; 60-34-4; 62-53-3; 629-82-3; 64-04-0; 64-17-5; 64-19-7; 67-56-1; 67-63-0; 67-64-1; 67-66-3; 68-12-2; 693-65-2; 71-23-8; 71-36-3; 71-43-2; 7395-10-0; 74-89-5; 74-90-8; 75-04-7; 75-05-8; 75-09-2; 75-15-0; 75-31-0; 75-50-3; 75-52-5; 75-56-9; 75-65-0; 75-76-3; 76-05-1; 7664-41-7; 7723-14-0; 7782-65-2; 7784-42-1; 78-10-4; 78-81-9; 78-83-1; 78-92-2; 78-93-3; 7803-51-2; 7803-52-3; 7803-62-5; 79-01-6; 79-34-5; 80-56-8; 84-77-5; 872-50-4; 88-72-2; 90-11-9; 90-13-1; 91-17-8; 91-22-5; 91-66-7; 917-72-6; 92-51-3; 93-89-0; 95-46-5; 96-22-0; 98-01-1; 98-82-8; 98-86-2; 98-95-3; 998-30-1;
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