IUPAC Solubility Publication

INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY
ANALYTICAL CHEMISTRY DIVISION
COMMISSION ON SOLUBILITY DATA

SOLUBILITY DATA SERIES

Editor-in-Chief
A. S. KERTES

Volume 23
COPPER, SILVER, GOLD AND ZINC, CADMIUM, MERCURY OXIDES AND HYDROXIDES

Volume Editors
T. P. DIRKSE	Calvin College Grand Rapids, Michigan 49506, USA

Contributors
T. MICHALOWSKI	Jagie/Ionian University Krakow, Poland
F. IZUMI	Gunma University Kiryu, Japan
H. AKAIWA	National Institute for Research in Inorganic Materials, lbaraki, Japan

Copyright © 1986 International Union of Pure and Applied Chemistry

Contents			v
Foreword			vii
Preface			x
Introduction: The solubility of solids in liquids			xii

1.	Copper (I) oxide
	1.1	Evaluation of aqueous systems	1
	1.2	Binary aqueous systems	4
	1.3	Ternary aqueous system, one saturating component	7
	1.4	Multicomponent aqueous system, one saturating component	8
	1.5	Organic solvent system	9
2.	Copper (II) oxide and hydroxide
	2.1	Evaluation of aqueous systems	10
	2.2	Binary aqueous systems	27
	2.3	Ternary aqueous systems, one saturating comonent	34
	2.4	Multicomponent aqueous systems, one saturating component	63
	2.5	Multicomponent aqueous system, two saturating components	81
	2.6	Organic solvent system	82
3.	Silver (I) oxide
	3.1	Evaluation of aqueous systems	83
	3.2	Binary aqueous systems	98
	3.3	Ternary aqueous systems, one saturating component	108
	3.4	Ternary aqueous system, two saturating components	135
	3.5	Multicomponent aqueous systems, one saturating component	138
4.	Silver (II) oxide
	4.1	Evaluation of aqueous systems	144
	4.2	Ternary aqueous systems, one saturating component	146
5.	Gold (III) hydroxide
	5.1	Evaluation of aqueous systems	148
	5.2	Ternary aqueous systems, one saturating component	151
6.	Zinc oxide and hydroxide
	6.1	Evaluation of aqueous systems	156
	6.2	Binary aqueous systems	185
	6.3	Ternary aqueous systems, one saturating component	192
	6.4	Multicomponent aqueous systems, one saturating component	264
7.	Cadmium oxide and hydroxide
	7.1	Evaluation of aqueous systems	270
	7.2	Binary aqueous systems	283
	7.3	Ternary aqueous systems, one saturating component	286
	7.4	Multicomponent aqueous systems, one saturating component	300
8	Mercury (II) oxide
	8.1	Evaluation of aqueous systems	307
	8.2	Binary aqueous system	318
	8.3	Ternary aqueous systems, one saturating component	319
	8.4	Multicomponent aqueous systems, one saturating component	335
System Index			343
Registry Number Index			351
Author Index			353

Chemical Substances

1-propanol; 2-aminoethanol; 2-propanone; Acetic acid; Acetic acid, methyl ester; Acetic acid, sodium salt; Acetonitrile; Ammonia; Ammonium carbonate; Ammonium chloride; Ammonium hydroxide; Ammonium sulfate; Ammonium thiocyanate; Arsenic (V) oxide; Arsenic (VI) oxide; Barium hydroxide; Barium nitrate; Benzenamine; Boron (III) oxide; Bromine; Cadmium hydroxid; Cadmium hydroxide; Cadmium oxide; Cadmium perchlorate; Cadmium sulfate; Carbon dioxide; Carbonic acid, ammonium; Carbonic acid, ammonium salt; Carbonic acid, sodium salt; Carton dioxide; Chromium (VI) oxide; Copper; Copper (I) oxide; Copper (II) hydroxide; Copper (II) oxide; Copper (III); Copper (Ill) oxide; Ethanol; Ethanol , 2,2',2"- nitrilotri-; Ethanol , 2,2',2"-nitrilotri; Ethanol , 2,2'-imino; Ethanol , 2,2'-imino; Ethanol , 2,2'-imino-; Ethanol , 2-amino-; Ethanol 2,2",2"-nitrilotri; Glucose; Glycine; Gold (III) hydroxide; Hydrochloric acid; Hydrofluoric acid; Hydrogen peroxide; Hydroxide; Hydroxide Ethanol , 2-arrino-; Lithium chloride; Lithium hydroxide; Magnesium chloride; Mercury (II) oxide; Methanamine; Methanol; Nitric acid; Nitric acid, ammonium salt; Nitric acid, barium; Nitric acid, barium salt; Nitric acid, potassium salt; Nitric acid, sodium salt; Perchlc-ric acid, copper salt; Perchloric acid; Perchloric acid, cadmium salt; Perchloric acid, copper (II) salt; Perchloric acid, sodium; Perchloric acid, sodium salt; Phosphoric acid; Phosphorus (V) oxide; Potassium chloride; Potassium fluoride; Potassium hydroxide; Potassium nitrate; Potassium sulfate; Pyridine; Salt; Seawater; Selenium (IV) oxide; Selenium oxide; Silver (I) hydroxide; Silver (I) oxide; Silver (II) oxide; Sodium chloride; Sodium hydroxide; Sodium hydroxide perchlorate; Sodium perchlorate; Sodium sulfate; Sodium sulfide; Sucrose; Sulfate sulfuric acid, sodium; Sulfur dioxide; Sulfur trioxide; Sulfuric acid; Sulfuric acid, ammonium; Sulfuric acid, ammonium salt; Sulfuric acid, cadmium salt; Sulfuric acid, copper salt; Sulfuric acid, potassium salt; Sulfuric acid, sodium salt; Sulfuric acid, zinc salt; Thiocyanic acid, ammonium salt; Urea; Water; Zinc; Zinc chloride; Zinc hydroxide; Zinc oxide;

CAS Registry Numbers

50-99-7; 56-40-6; 57-13-6; 57-50-1; 62-53-3; 64-17-5; 64-19-7; 67-56-1; 67-64-1; 71-23-8; 74-89-5; 75-05-8; 79-20-9; 102-71-6; 110-86-1; 120-71-6; 111-42-2; 124-38-9; 127-09-3; 141-43-5; 497-19-8; 506-87-6; 1301-96-8; 1303-28-2; 1303-52-2; 1303-86-2; 1306-19-0; 1310-58-3; 1310-65-2; 1310-73-2; 1313-82-2; 1314-13-2; 1314-56-3; 1317-38-0; 1317-39-1; 1333-82-0; 1336-21-6; 1762-95-4; 6484-52-2; 7446-08-4; 7446-09-5; 2025949; 7447-40-7; 7447-41-8; 7601-89-0; 7601-90-3; 7631-99-4; 7646-85-7; 7647-01-0; 7647-14-5; 7664-38-2; 7664-39-3; 7664-41-7; 7664-93-9; 7697-37-2; 7722-84-1; 7726-95-6; 7732-18-5; 7733-02-0; 7757-79-1; 7757-82-6; 7758-98-7; 7761-88-8; 7778-80-5; 7783-20-2; 7786-30-3; 7789-23-3; 10022-31-8; 10124-36-4; 12125-02-9; 12258-15-0; 13770-18-8; 17194-00-2; 20427-58-1; 20427-59-2; 20667-12-3; 21041-95-2; 21908-53-2; 35089-90-8;