IUPAC Solubility Publication

INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY
ANALYTICAL CHEMISTRY DIVISION
COMMISSION ON SOLUBILITY DATA

SOLUBILITY DATA SERIES

Editor-in-Chief
A. S. KERTES

Volume 26
SULFITES, SELENITES AND TELLURITES

Volume Editors
MARY R. MASSON	University of Aberdeen Scotland, UK

Co-Editors
H. D. LUTZ	University of Siegen Federal Republic of Germany
B. ENGELEN	University of Siegen Federal Republic of Germany

Contributors
M. R. MASSON
H. D. LUTZ
B. ENGELEN
Copyright © 1986 International Union of Pure and Applied Chemistry

Contents			v
Foreword			viii
Preface			xi
Introduction to the Solubility of Solids in Liquids			xvi

1.	Sodium Bisulfite
	1.1	Evaluation	1
	1.2	Binary system	8
	1.3	Ternary systems	16
	1.4	More complex systems	59
2.	SodIum pyrosulfIte (sodIum dIsulflte)
	2.1	Evaluation	72
	2.2	Binary system	72
	2.3	Ternary systems	76
	2.4	More complex systems	78
3.	Potassium sulfite
	3.1	Evaluation	90
	3.2	Binary system	93
	3.3	Ternary systems	95
	3.4	More complex systems	107
4.	Potassium pyrosulfite (potassium disulfite)
	4.1	Evaluation	108
	4.2	Binary system	110
5.	Ammonium sulfite
	5.1	Evaluation	113
	5.2	Binary system	117
	5.3	Ternary systems	121
	5.4	More complex systems	141
6.	Ammonium pyrosulfite (ammonium disulfite)
	6.1	Evaluation	144
	6.2	Binary system	146
	6.3	Ternary systems	147
7.	Beryllium sulfite		152

8.	Magnesium sulfite
	8.1	Evaluation	153
	8.2	Binary system	160
	8.3	Ternary systems	165
	8.4	More complex systems	180
9.	Calcium sulfite
	9.1	Evaluation	187
	9.2	Binary system	194
	9.3	Ternary systems	196
	9.4	More complex systems	220
10.	Strontium sulfite		236

11.	Barium sulfite		240

12.	Manganese (II) sulfite		248

13.	Iron(II) sulfite		252

14.	Cobalt (II) sulfite		256

15.	Nickel (II) sulfite		258

16..	Copper (I) sulfite		260

17.	Copper (I,II) sulfite		262

18.	Silver sulflte		267

19.	Zinc sulfite		271

20.	Cadmium sulfite		286

21.	Mercury (I) sulfite		291

22..	Lead (II) sulfite		293

23.	Sodium selenite		303

24.	Potassium selenite		322

25.	Alkali-metal selenites
	25.1	Evaluation	331
	25.2	Lithium selenite	332
	25.3	Sodium pyroselenite (sodium diselenite)	333
	25.4	Sodium trihydrogen diselenite	336
	25.5	Potassium pyroselenite (diselenite)	338
	25.6	Potassium trihydrogen diselenite	340
	25.7	Ammonium selenite	342
	25.8	Ammonium pyroselenite (diselenite)	344
	25.9	Ammonium trihydrogen diselenite	346
26.	Sparingly soluble selenites
	26.1	Evaluation	348
	26.2	Beryllium selenite	353
	26.3	Magnesium selenite	354
	26.4	Calcium selenite	356
	26.5	Strontium selenite	358
	26.6	Barium selenite	362
	26.7	Manganese (II) selenite	367
	26.8	Iron (III) selenite	368
	26.9	Cobalt (II) selenite	370
	26.10	Nickel (II) selenite	374
	26.11	Copper (II) selenite	377
	26.12	Silver selenite	380
	26.13	Zinc selenite	389
	26.14	Cadmium selenite	391
	26.15	Mercury (I) selenite	394
	26.16	Mercury (II) selenite	397
	26.17	Lead (II) selenite	401
27.	Tellurites (salts of the tellurate (IV) ion)
	27.1	Evaluation	403
	27.2	Lithium tellurite	406
	27.3	Sodium tellurite	407
	27.4	Cesium tellurite	419
	27.5	Barium tellurite	420
	27.6	Cobalt (II) tellurite	421
	27.7	Nickel (II) tellurite	422
	27.8	Copper (II) tellurite	423
	27.9	Silver tellurite	424
	27.1	Lead (II) tellurite	427
System Index			429
Registry Number Index			443
Author Index			446

CAS Registry Numbers

10026-23-0; 10035-03-7; 10101-41-4; 10101-96-9; 10102-15-5; 10102-18-8; 10102-20-2; 10117-38-1; 10124-36-4; 10192-30-0; 10196-04-0; 10214-40-1; 10257-55-3; 10294-49-2; 10431-47-7; 111-42-2; 12125-02-9; 12529-99-6; 127-09-3; 1310-58-3; 1310-73-2; 1314-56-3; 1336-21-6; 13410-01-0; 13446-29-2; 1344-81-0; 13450-81-2; 13451-02-0; 13465-98-0; 13477-23-1; 135-19-3; 13568-71-3; 13597-44-9; 13597-46-1; 13718-59-7; 13774-25-9; 13812-58-3; 13814-59-0; 13814-81-8; 14013-56-0; 141-53-7; 14459-36-0; 14460-28-7; 14590-38-6; 14899-38-8; 15122-56-2; 15293-86-4; 15457-71-3; 15457-72-4; 15593-51-8; 15593-61-0; 15702-34-8; 15851-44-2; 15851-47-5; 15851-51-2; 15855-76-2; 15855-80-8; 15857-44-0; 15899-92-0; 16731-55-8; 19086-20-5; 20911-44-8; 20911-45-9; 21006-12-1; 22451-06-5; 24458-98-8; 25425-97-2; 25454-04-0; 26970-82-1; 29501-28-8; 32702-66-2; 32736-64-4; 35788-00-2; 3597-78-9; 3780-18-2; 38333-62-9; 40854-09-9; 41292-05-1; 41292-06-2; 471-34-1; 4929-69-2; 497-19-8; 50-99-7; 51092-74-1; 57-13-6; 584-08-7; 58-86-6; 60365-38-0; 60936-55-2; 60943-67-1; 631-61-8; 64-17-5; 64-19-7; 6484-52-2; 65410-83-5; 65410-84-6; 66516-57-2; 72860-77-6; 72878-03-6; 7446-08-4; 7446-09-5; 7446-10-8; 7487-88-9; 7488-51-9; 7488-52-0; 75042-11-4; 75042-12-5; 75042-13-6; 7601-54-9; 7601-89-0; 7601-90-3; 7631-14-5; 7631-90-5; 7631-99-4; 7647-01-0; 7647-14-5; 7664-41-7; 7664-93-9; 7681-57-4; 7697-37-2; 7732-18-5; 7733-02-0; 7757-79-1; 7757-82-6; 7757-83-7; 7757-88-2; 7757-93-9; 7757-95-1; 7758-09-0; 7758-98-7; 7772-04-7; 7773-08-4; 7775-14-6; 7778-18-9; 7778-80-5; 7782-70-9; 7782-82-3; 7782-99-2; 7783-00-8; 7783-11-1; 7783-18-8; 7783-19-9; 7783-20-2; 7784-05-6; 7786-30-3; 7787-39-5; 77902-26-2; 77902-27-3; 77902-28-4; 77-92-9; 8062-15-5; 83534-22-9; 83753-29-1; 875-83-2; 89146-33-8; 91498-96-3; 91498-97-4; 96247-21-1;